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Group 2 Metal Complexes Based on Redox-Active Acenaphthene-1,2-Diimine Ligand for the Polymerization of L-Lactide

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Magnesium and calcium coordination compounds (dpp-bian)Ca(thf)4 (1), (dpp-bian)2Mg (2), and (dpp-bian)2Ca (3), containing a chelating redox-active acenaphthenediimine ligand, dpp-bian {1,2-bis-[(2,6-diisopropyl)phenylimino]acenaphthene}, were studied as L-lactide ring-opening polymerization catalysts. The interaction of complex 1 with L-lactide in solution was studied by ESR spectroscopy. The solvent effect on the polymerization rate and molecular-mass characteristics of the polymers obtained was demonstrated.

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References

  1. Dechy-Cabaret, O., Martin-Vaca, B., and Bourissou, D., Chem. Rev., 2004, vol. 104, no. 12, pp. 6147–6176.

    Article  CAS  Google Scholar 

  2. Middleton, J.C. and Tipton, A.J., Biomaterials, 2000, vol. 21, no. 23, pp. 2335–2346.

    Article  CAS  Google Scholar 

  3. Jamshidian, M., Tehrany, E.A., Imran, M., et al., Compr. Rev. Food Sci. Food Saf., 2010, vol. 9, no. 5, pp. 552–571.

    Article  CAS  Google Scholar 

  4. Urayama, H., Moon, S.I., and Kimura. Y., Macromol. Mater. Eng., 2003, vol. 288, no. 2, pp. 137–143.

    Article  CAS  Google Scholar 

  5. Migliaresi, C., Fambri, L., and Cohn, D., J. Biomater. Sci., Polym. Ed., 1994, vol. 5, no. 6, pp. 591–606.

    Article  CAS  Google Scholar 

  6. Grayson, A.C.R., Voskerician, G., Lynn, A., et al., J. Biomater. Sci., Polym. Ed., 2004, vol. 15, no. 10, pp. 1281–1304.

    Article  CAS  Google Scholar 

  7. Carpentier, J.F. and Sarazin, Y., Alkaline-Earth Metal Compounds: Oddities and Applications, Harder, S., Ed., Berlin: Springer, 2013, pp. 141–189.

  8. Chisholm, M.H. and Eilerts, N.W., ChemComm, 1996, no. 7, pp. 853–854.

    Google Scholar 

  9. Chisholm, M.H., Eilerts, N.W., Huffman, J.C., et al., J. Am. Chem. Soc., 2000, vol. 122, no. 48, pp. 11845–11854.

    Article  CAS  Google Scholar 

  10. Chisholm, M.H., Huffman, J.C., and Phomphrai, K., J. Chem. Soc., Dalton Trans., 2001, no. 3, pp. 222–224.

    Article  Google Scholar 

  11. Chisholm, M.H., Gallucci, J., and Phomphrai, K., Inorg. Chem., 2002, vol. 41, no. 10, pp. 2785–2794.

    Article  CAS  PubMed  Google Scholar 

  12. Chamberlain, B.M., Cheng, M., Moore, D.R., et al., J. Am. Chem. Soc., 2001, vol. 123, no. 14, pp. 3229–3238.

    Article  CAS  PubMed  Google Scholar 

  13. Ayala, C.N., Chisholm, M.H., Gallucci, J.C., and Krempner, C., Dalton Trans., 2009, no. 42, pp. 9237–9245.

    Article  CAS  Google Scholar 

  14. Chisholm, M.H., Gallucci, J., and Phomphrai, K., ChemComm, 2003, no. 1, pp. 48–49.

    Google Scholar 

  15. Chisholm, M.H., Gallucci, J.C., and Phomphrai, K., Inorg. Chem., 2004, vol. 43, no. 21, pp. 6717–6725.

    Article  CAS  PubMed  Google Scholar 

  16. Sanchez-Barba, L.F., Garces, A., Fajardo, M., et al., Organometallics, 2007, vol. 26, no. 25, pp. 6403–6411.

    Article  CAS  Google Scholar 

  17. Sanchez-Barba, L.F., Garces, A., Fernandez-Baeza, J., et al., Organometallics, 2011, vol. 30, no. 10, pp. 2775–2789.

    Article  CAS  Google Scholar 

  18. Garces, A., Sanchez-Barba, L.F., Alonso-Moreno, C., et al., Inorg. Chem., 2010, vol. 49, no. 6, pp. 2859–2871.

    Article  CAS  PubMed  Google Scholar 

  19. Poirier, V., Roisnel, T., Carpentier, J.F., and Sarazin, Y., Dalton Trans., 2009, no. 44, pp. 9820–9827.

    Article  CAS  Google Scholar 

  20. Ejfler, J., Krauzy-Dziedzic, K., Szafert, S., et al., Eur. J. Inorg. Chem., 2010, no. 23, pp. 3602–3609.

    Article  CAS  Google Scholar 

  21. Nifant’ev, I.E., Shlyakhtin, A.V., Bagrov, V.V., et al., Dalton Trans., 2017, vol. 46, no. 36, pp. 12132–12146.

    Article  PubMed  Google Scholar 

  22. Sarazin, Y., Howard, R.H., Hughes, D.L., Humphrey, S.M., and Bochmann, M., Dalton Trans., 2006, no. 2, pp. 340–350.

    Article  Google Scholar 

  23. Chen, H.-Y., Tang, H.-Y., and Lin, C.-C., Polymer, 2007, vol. 48, no. 8, pp. 2257–2262.

    Article  CAS  Google Scholar 

  24. Fedushkin, I.L., Morozov, A.G., Chudakova, V.A., et al., Eur. J. Inorg. Chem., 2009, no. 33, pp. 4995–5003.

    Article  CAS  Google Scholar 

  25. Morozov, A.G., Fedyushkin, I.L., and Aleinik, D.Y., Russ. J. Appl. Chem., 2016, vol. 89, no. 12, pp. 2095–2101.

    Article  CAS  Google Scholar 

  26. Paulovicova, A., El-Ayaan, U., Shibayama, K., et al., Eur. J. Inorg. Chem., 2001, no. 10, pp. 2641–2646.

    Article  Google Scholar 

  27. Fedushkin, I.L., Skatova, A.A., Chudakova, V.A., et al., Eur. J. Inorg. Chem., 2003, no. 18, pp. 3336–3346.

    Article  CAS  Google Scholar 

  28. Fedushkin, I.L., Skatova, A.A., Chudakova, V.A., et al., Russ. Chem. Bull., 2004, vol. 53, no. 10, pp. 2142–2147.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 29, Nizhny Novgorod, 603137, Russia

    A. G. Morozov, E. S. Markelova & I. L. Fedyushkin

Authors
  1. A. G. Morozov
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  2. E. S. Markelova
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  3. I. L. Fedyushkin
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Correspondence to A. G. Morozov.

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Original Russian Text © A.G. Morozov, E.S. Markelova, I.L. Fedyushkin, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 6, pp. 899−904.

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Morozov, A.G., Markelova, E.S. & Fedyushkin, I.L. Group 2 Metal Complexes Based on Redox-Active Acenaphthene-1,2-Diimine Ligand for the Polymerization of L-Lactide. Russ J Appl Chem 91, 1044–1048 (2018). https://doi.org/10.1134/S1070427218060253

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  • DOI: https://doi.org/10.1134/S1070427218060253

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