Skip to main content
SpringerLink
Log in

Desulfurization of Diesel over Ni/ZnO Adsorbent Prepared by Coprecipitation

  • Sorption and Ion Exchange Processe
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Ni/ZnO adsorbents with various Ni/Zn molar ratios were prepared by coprecipitation; their adsorption capacity in reactive adsorption desulfurization (RADS) of diesel oil was investigated. Ni/ZnO exhibits much higher adsorption performance than pure Ni and pure ZnO. The Ni content plays a crucial role in determining RADS activity over Ni/ZnO; the sulfur capacity depends on the ZnO content in Ni/ZnO. The Ni4/Zn6 adsorbent shows the optimal performance; the sulfur content in diesel oil is reduced to less than 5 ppm in first 60 h and less than 15 ppm in next 68 h.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Al-Ghouti, M.A. and Al-Degs, Y.S., Korean J. Chem. Eng., 2015, vol. 32, pp. 278–285.

    Article  CAS  Google Scholar 

  2. Yang, R.T., Hernández-Maldonado, A.J., and Yang, F.H., Science, 2003, vol. 301, pp. 79–81.

    Article  CAS  PubMed  Google Scholar 

  3. Ma, X., Velu, S., Kim, J.H., and Song, C., Appl. Catal. B, 2005, vol. 56, pp. 137–147.

    Article  CAS  Google Scholar 

  4. Rodriguez, J.A. and Hrbek, J., Acc. Chem. Res., 1999, vol. 32, pp. 719–728.

    Article  CAS  Google Scholar 

  5. Cychosz, K.A., Wong-Foy, A.G., and Matzger, A.J., J. Am. Chem. Soc., 2009, vol. 131, pp. 14538–14543.

    Article  CAS  PubMed  Google Scholar 

  6. Babich, I.V. and Moulijn, J.A., Fuel, 2003, vol. 82, pp. 607–631.3.

    Article  CAS  Google Scholar 

  7. Huang, L.C., Wang, G.F., Qin, Z.F., et al., Appl. Catal. B, 2011, vol. 106, pp. 26–38.

    CAS  Google Scholar 

  8. Tawara, K., Nishimura, T., Iwanami, H., et al., Ind. Eng. Chem. Res., 2001, vol. 40, pp. 2367–2370.

    Article  CAS  Google Scholar 

  9. Tawara, K., Nishimura, T., and Iwanami, H., Sekiyu Gakkaishi, 2000, vol. 43, pp. 114–120.

    Article  CAS  Google Scholar 

  10. Tawara, K., Nishimura, T., Iwanami, H., et al., Sekiyu Gakkaishi, 2001, vol. 44, pp. 43–51.

    Article  CAS  Google Scholar 

  11. Ryzhikov, A., Bezverkhyy, I., and Bellat, J.-P., Appl. Catal. B, 2008, vol. 84, pp. 766–772.

    Article  CAS  Google Scholar 

  12. Bezverkhyy, I., Ryzhikov, A., Gadacz G., and Bellat, J.P., Catal. Today, 2008, vol. 130, pp. 199–205.

    Article  CAS  Google Scholar 

  13. Bezverkhyy, I., Safonova, O.V., Afanasiev, P., and Bellat, J.-P., J. Phys. Chem. C, 2009, vol. 113, pp. 17064–17069.

    Article  CAS  Google Scholar 

  14. Huang, L.C., Wang, G.F., Qin, Z.F., et al., Catal. Commun., 2010, vol. 11, pp. 592–596.

    Article  CAS  Google Scholar 

  15. Huang, L.C., Qin, Z.F., Wang, G.F., et al., Ind. Eng. Chem. Res., 2010, vol. 49, pp. 4670–4675.

    Article  CAS  Google Scholar 

  16. Yang, Y.X., Zhang, Y.L., Wang, L., et al., Shiyou Huagong, 2008, vol. 37, pp. 243–246.

    CAS  Google Scholar 

  17. Petzold, F.G., Jasinski, J., Clark, E.L., et al., Catal. Today, 2012, vol. 198, pp. 219–227.

    Article  CAS  Google Scholar 

  18. Zhang, Y.L., Yang, Y.X., Han, H.X., et al., Appl. Catal. B, 2012, vol. 119–120, pp. 13–19.

    Article  CAS  Google Scholar 

  19. Gupta, M., He, J., Nguyen, T., et al., Appl. Catal. B, 2016, vol. 180, pp. 246–254.

    Article  CAS  Google Scholar 

  20. US Patent 6274533, Publ. 2001.

  21. Shaheen, W.M., Mater. Lett., 2002, vol. 52, pp. 272–282.

    Article  CAS  Google Scholar 

  22. Henmi, H., Mori, M., Hirayama, T., et al., Thermochim. Acta, 1986, vol. 104, pp. 101–109.

    Article  CAS  Google Scholar 

  23. Liu, Y.H., Zhao, J.Z., Zhang, H., et al., Thermochim. Acta, 2004, vol. 414, pp. 121–123.

    Article  CAS  Google Scholar 

  24. Arena, F., Barbera, K., Italiano, G., et al., J. Catal., 2007, vol. 249, pp. 185–194.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ordos Dalu Institute of Coal Chemical Industry, Ordos, Inner Mongolia, 010320, China

    Lichun Huang & Lai Yan

  2. Synfuels China Inner Mongolia Co., Ltd., Ordos, Inner Mongolia, 010320, China

    Lichun Huang & Lai Yan

  3. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, Shanxi, 030001, China

    Hui Ge

Authors
  1. Lichun Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hui Ge
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Lai Yan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Lichun Huang.

Additional information

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Huang, L., Ge, H. & Yan, L. Desulfurization of Diesel over Ni/ZnO Adsorbent Prepared by Coprecipitation. Russ J Appl Chem 91, 833–838 (2018). https://doi.org/10.1134/S1070427218050154

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427218050154

Search

Navigation