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Experimental and Simulation Research of Spatial Distribution of Carbonyl Groups in γ-Irradiated Polyethylene

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The dependence of the optical density in the peak of the characteristic IR absorption band of carbonyl groups on the thickness of polyethylene films irradiated with 60Co gamma quanta is experimentally determined. A method for calculating the distribution of CO groups relative to the frontal surfaces of the samples is proposed and justified. The calculated curves are discussed in terms of the generally accepted model of diffusion-controlled oxidation of polymers under the action of high energy radiation. Based on the data obtained, the conditions for the radiation modification of polymers are found, which make it possible to minimize the destructive effects of oxidation.

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References

  1. Chmielewski, A.G., Chmielewska, D.K., Michalik, J., et al., Nucl. Instr. Meth. Phys. Rec. B, 2007, vol. 265, pp. 339–346.

    Article  CAS  Google Scholar 

  2. Rosiak, J.M. and Olejniczak, J., Radiat. Phys. Chem., 1993, vol. 42, nos. 4–6, pp. 903–906.

    Article  CAS  Google Scholar 

  3. Komarov, F.F., Physics-Uspekhi, 2003, vol. 46, no. 12, pp. 1253–1282.

    Article  CAS  Google Scholar 

  4. Insepov, Z., Norem, J., Swenson, D.R., et al., Vacuum, 2008, vol. 82, pp. 872–879.

    Article  CAS  Google Scholar 

  5. Khatipov, S.A. and Artamonov, N.A., Ross. Khim. Zh., 2008, vol. LII, no. 3, pp. 89–97.

    Google Scholar 

  6. Zenin, A.A., Feldman, V.I., Shmakova, N.A., et al., Nucl. Instr. Meth. Phys. Rec. B, 2007, vol. 265, pp. 334–338.

    Article  CAS  Google Scholar 

  7. Lugao, A.B., Malmonge, S.M., Nucl. Instr. Meth. Phys. Rec. B, 2001, vol. 185, nos. 1–4, pp. 37–42.

    Article  CAS  Google Scholar 

  8. Kozlovskiy, A., Zhanbotion, A., Zdorovets, M. et al., Nucl. Instr. Meth. Phys. Rec. B, 2016, vol. 381, pp. 103–109.

    Article  CAS  Google Scholar 

  9. Guizhi, W., Zongitao, L., and Zhengwen, W., Radiat. Phys. Chem., 1993, vol. 42, nos. 1–3, pp. 107–108.

    Article  Google Scholar 

  10. Polymer Grafting and Crosslinking, Bhatta charya, A., Rawlins, W., and Ray, P., USA: Wiley, 2009.

  11. Bykov, Ye.V., Bistritskaya, Ye.V., and Karpukhin, O.N., Polym. Sci. USSR, 1987, vol. 29, no. 7, pp. 1479–1485.

    Article  Google Scholar 

  12. Dalinkevich, A.A., Piskarev, I.M., and Shlyapnikov, Yu.A., Polym. Degrad. Stab., 1993, vol. 40, pp. 117–119.

    Article  CAS  Google Scholar 

  13. Dalinkevich, A.A., Kiryushkin, S.G., and Shlyapnikov, Yu.A., Vysokomol. Soedin., 1991, vol. 33B, no. 12, pp. 883–893.

    Google Scholar 

Download references

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Authors and Affiliations

  1. St. Petersburg State Technological Institute (Technical University), Moskovskii pr. 26, St. Petersburg, 190013, Russia

    A. A. Akatov & A. F. Nechaev

Authors
  1. A. A. Akatov
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  2. A. F. Nechaev
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Correspondence to A. F. Nechaev.

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Original Russian Text © A.A. Akatov, A.F. Nechaev, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 3, pp. 385−388.

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Akatov, A.A., Nechaev, A.F. Experimental and Simulation Research of Spatial Distribution of Carbonyl Groups in γ-Irradiated Polyethylene. Russ J Appl Chem 91, 424–427 (2018). https://doi.org/10.1134/S1070427218030138

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  • DOI: https://doi.org/10.1134/S1070427218030138

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