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Thermodynamic Analysis and Kinetics of Etching of Thin PbS Films in Hydrochloric Acid Solutions

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

A hydrochloric acid solution of hydrogen peroxide was suggested for etching lead sulfide films. The solubility of lead sulfide in relation to the hydrochloric acid concentration in the etching solution was calculated using thermodynamic analysis, taking into account the stability of lead complex species. The kinetics of hydrogen peroxide decomposition in the hydrochloric acid solution was studied, and the formal rate equation of the process was constructed.

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Authors and Affiliations

  1. Ural Federal University named after the first president of Russia B.N. Yeltsin, Yekaterinburg, 620075, Russia

    S. S. Tulenin, D. A. Novotorkina, M. S. Rogovoy, K. A. Karpov, A. V. Pozdin, L. N. Maskaeva & V. F. Markov

  2. Ural Institute of State Fire Service, EMERCOM of Russia, ul. Mira 22, Yekaterinburg, 620137, Russia

    L. N. Maskaeva & V. F. Markov

Authors
  1. S. S. Tulenin
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  2. D. A. Novotorkina
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  3. M. S. Rogovoy
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  4. K. A. Karpov
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  5. A. V. Pozdin
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  6. L. N. Maskaeva
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  7. V. F. Markov
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Corresponding author

Correspondence to S. S. Tulenin.

Additional information

Original Russian Text © S.S. Tulenin, D.A. Novotorkina, M.S. Rogovoy, K.A. Karpov, A.V. Pozdin, L.N. Maskaeva, V.F. Markov, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 3, pp. 319−327.

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Tulenin, S.S., Novotorkina, D.A., Rogovoy, M.S. et al. Thermodynamic Analysis and Kinetics of Etching of Thin PbS Films in Hydrochloric Acid Solutions. Russ J Appl Chem 91, 360–367 (2018). https://doi.org/10.1134/S1070427218030023

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  • DOI: https://doi.org/10.1134/S1070427218030023

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