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Preparation of Ultramicroporous Materials by Fluidized-Bed Pyrolytic Deposition of Carbon in Pores of a Carbon Matrix

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Abstract

Samples of microporous materials were prepared by pyrolytic deposition of carbon from divinyl in a fluidized bed reactor onto carbon supports obtained from coconut and pine nut shells. The influence exerted on the adsorption capacity for CO2 by the divinyl pyrolysis temperature (in the range 600–750°С) and degree of densification (in the range 6–22%) was studied. Carbon deposition conditions ensuring the specific surface area (SBET) lower than 5 m2 g–1 at the adsorption capacity for СО2 higher than 1 mmol g–1 for both samples were found.

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References

  1. Pribylov, A.A., Kalinnikova, I.A., and Murdmaa, K.O., Russ. Chem. Bull., 2015, vol. 64, no. 4, pp. 819–824.

    Article  CAS  Google Scholar 

  2. P’yanova, L.G., Baklanova, O.N., Drozdov, V.A., et al., Khim. Inter. Ustoich. Razv., 2014, vol. 22, pp. 633–641.

    Google Scholar 

  3. Sethupathi S., Bashir M.J.K, Akbar Z.A., et al., Waste Manag. Res., 2015, vol. 33, N 4, pp. 303–312.

    Article  CAS  Google Scholar 

  4. Rodrigues S.C., Whitley R., and Mendes, A., J. Membr. Sci., 2014, vol. 459, pp. 207–216.

    Article  CAS  Google Scholar 

  5. Thommes, M., Kaneko, K., Neimark, A.V., et al., Pure Appl. Chem., 2015, pp. 1–19.

    Google Scholar 

  6. Berveno, A.V. and Berveno, V.P., Polzun. Vestn. (Barnaul), 2009, no. 3, pp. 189–191.

    Google Scholar 

  7. Muniandy, L., Adam, F., Mohamed, A.R., and Ng, E.-P., Microp. Mesop. Mater., 2014, vol. 197, pp. 316–323.

    Article  CAS  Google Scholar 

  8. Shi, J.-L., Tang, C., Peng, H.-J., et al., Small, 2015, vol. 11, no. 39, pp. 5243–5252.

    Article  CAS  Google Scholar 

  9. Minkowycz, W.J., Sparrow, E.M., and Murthy, J.Y., Handbook of Numerical Heat Transfer, Wiley, 2009, p. 984.

    Google Scholar 

  10. Garcia-Martinez, J., Gazorla-Amoros, D., and Linares-Solano, A., Studies in Surface Science and Catalysis, Unger, K.K., et al., Eds., Elsevier, 2000, vol. 128, pp. 485–494.

    CAS  Google Scholar 

  11. Fenelonov, V.B., Vvedenie v fizicheskuyu khimiyu formirovaniya supramolekulyarnoi struktury adsorbentov i katalizatorov (Introduction to Physical Chemistry of Supramolecular Structure Formation in Adsorbents and Catalysts), Novosibirsk: Sibirskoe Otdel. Ross. Akad. Nauk, 2002.

    Google Scholar 

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Correspondence to E. A. Raiskaya.

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Original Russian Text © E.A. Raiskaya, G.G. Saveleva, V.A. Drozdov, O.B. Belskaya, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 11, pp. 1640−1645.

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Raiskaya, E.A., Saveleva, G.G., Drozdov, V.A. et al. Preparation of Ultramicroporous Materials by Fluidized-Bed Pyrolytic Deposition of Carbon in Pores of a Carbon Matrix. Russ J Appl Chem 90, 1969–1973 (2017). https://doi.org/10.1134/S1070427217120114

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  • DOI: https://doi.org/10.1134/S1070427217120114

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