Advertisement

Russian Journal of Applied Chemistry

, Volume 90, Issue 12, pp 1944–1952 | Cite as

Hydrodeoxygenation of Vegetable Oil on NiMoS/WO3–Al2O3 Catalysts

  • A. A. Nepomnyashchiy
  • E. A. Buluchevskiy
  • A. V. Lavrenov
  • V. L. Yurpalov
  • T. I. Gulyaeva
  • N. N. Leont’eva
  • V. P. Talzi
Catalysis
  • 21 Downloads

Abstract

Tungstate-containing aluminum oxide is suitable as a catalyst support for hydrodeoxygenation of sunflower oil, ensuring 81–83 wt % yield of liquid products at 380°С, 4.0 MPa, and feed space velocity of 1 h–1. The catalyst acidity increases with increasing tungsten oxide content, leading to an increase in the content of decarboxylation/decarbonylation products and isoparaffins in the product mixture.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Choudhary, T.V. and Phillips, C.B., Appl. Catal., Ser. A, 2011, vol. 397, no. 1, pp. 1–12.Google Scholar
  2. 2.
    Mortensen, P.M., Grunwaldt, J.-D., Jensen, P.A., et al., Appl. Catal., Ser. A, 2011, vol. 407, no. 1, pp. 1–19.Google Scholar
  3. 3.
    Zhao, C., Bruck, T., and Lercher, J.A., Green Chem., 2013, vol. 15, no. 7, pp. 1720–1739.CrossRefGoogle Scholar
  4. 4.
    Bengoechea, M.O., Hertzberg, A., Miletić, N., et al., J. Anal. Appl. Pyrol., 2015, vol. 113, pp. 713–722.CrossRefGoogle Scholar
  5. 5.
    Herskowitz, M., Landau, M.V., Reizner, Y., and Berger, D., Fuel, 2013, vol. 111, pp. 157–164.CrossRefGoogle Scholar
  6. 6.
    Veriansyah, B., Han, J.Y., Kim, S.K., et al., Fuel, 2012, vol. 94, pp. 578–585.CrossRefGoogle Scholar
  7. 7.
    De Sousa, F.P., Cardoso, C.C., and Pasa, V.M.D., Fuel Process. Technol., 2016, vol. 143, pp. 35–42.CrossRefGoogle Scholar
  8. 8.
    Kubička, D. and Kaluža, L., Appl. Catal., Ser. A, 2010, vol. 372, no. 2, pp. 199–208.CrossRefGoogle Scholar
  9. 9.
    Besenbacher, F., Bronson, M., and Clausen, B.S., Catal. Today, 2008, vol. 130, pp. 86–96.CrossRefGoogle Scholar
  10. 10.
    Kubička, D. and Horáček, J., Appl. Catal., Ser. A, 2011, vol. 394, no. 1, pp. 9–17.CrossRefGoogle Scholar
  11. 11.
    Krár, M., Kovács, S., Kalló, D., and Hancsók, J., Bioresource Technol., 2010, vol. 101, no. 23, pp. 9287–9293.CrossRefGoogle Scholar
  12. 12.
    Hancsók, J., Kasza, T., Kovács, S., et al., J. Cleaner Prod., 2012, vol. 34, pp. 76–81.CrossRefGoogle Scholar
  13. 13.
    Kordouli, E., Sygellou, L., Kordulis, C., et al., Appl. Catal., Ser. B, 2017, vol. 209, pp. 12–22.CrossRefGoogle Scholar
  14. 14.
    Bie, Y., Lehtonen, J., and Kanervo, J., Appl. Catal., Ser. A, 2016, vol. 526, pp. 183–190.CrossRefGoogle Scholar
  15. 15.
    Gutierrez, A., Turpeinen, E.-M., Viljava, T.-R., and Krause, O., Catal. Today, 2017, vol. 285, pp. 125–134.CrossRefGoogle Scholar
  16. 16.
    Gusmao, J., Brodzki, D., Djéga-Mariadassou, G., and Frety, R., Catal. Today, 1989, vol. 5, no. 4, pp. 533–544.CrossRefGoogle Scholar
  17. 17.
    Guzman, A., Torres, J.E., Prada, L.P., and Nunez, M.L., Catal. Today, 2010, vol. 156, nos. 1–2, pp. 38–43.CrossRefGoogle Scholar
  18. 18.
    Da Rocha Filho, G., Brodzki, D., and Djéga-Mariadassou, G., Fuel, 1993, vol. 72, no. 4, pp. 543–549.CrossRefGoogle Scholar
  19. 19.
    Huber, G.W., O’Connor, P., and Corma, A., Appl. Catal., Ser. A, 2007, vol. 329, no. 1, pp. 120–129.CrossRefGoogle Scholar
  20. 20.
    Šimáček, P., Kubička, D., Šebor, G., and Pospíšil, M., Fuel, 2009, vol. 88, no. 3, pp. 456–460.CrossRefGoogle Scholar
  21. 21.
    Patent WO 2013050653A1, Publ. 2013.Google Scholar
  22. 22.
    Patent EP 1 728 844A1, Publ. 2006.Google Scholar
  23. 23.
    Brillouet, S., Baltag, E., Brunet, S., and Richard, F., Appl. Catal., Ser. B, 2011, vols. 148–149, pp. 201–211.Google Scholar
  24. 24.
    Wagenhofer, M.F., Barath, E., Gutierrez, O.Y., and Lercher, J.A., ACS Catal., 2017, vol. 7, no. 2, pp.1068−1076.Google Scholar
  25. 25.
    Şenol, O.I., Ryymin, E.-M., Viljava, T.-R., and Krause, A.O.I., J. Mol. Catal., Ser. A, 2007, vol. 277, nos. 1–2, pp. 107–112.Google Scholar
  26. 26.
    Coumans, A.E. and Hensen, E.J.M., Appl. Catal., Ser. B, 2017, vol. 201, pp. 290–301.CrossRefGoogle Scholar
  27. 27.
    Kubička, D., Horáček, J., Setnička, M., et al., Appl. Catal., Ser. B, 2014, vol. 145, pp. 101–107.CrossRefGoogle Scholar
  28. 28.
    Qian, E.W., Chen, N., and Gong, S., J. Mol. Catal., Ser. A, 2014, vol. 387, pp. 76–85.CrossRefGoogle Scholar
  29. 29.
    Madsen, A.T., Ahmed, E.H., Christensen, C.H., et al., Fuel, 2011, vol. 90, no. 11, pp. 3433–3438.CrossRefGoogle Scholar
  30. 30.
    Zarchin, R., Rabaev, M., Vidruk-Nehemya, R., et al., Fuel, 2015, vol. 139, pp. 684–691.CrossRefGoogle Scholar
  31. 31.
    Yang, Y., Wang, Q., Zhang, X., et al., Fuel Process. Technol., 2013, vol. 116, pp. 165–174.CrossRefGoogle Scholar
  32. 32.
    Sagata, K., Hirose, M., Hirano, Y., and Kita, Y., Appl. Catal., Ser. A, 2016, vol. 523, pp. 85–91.CrossRefGoogle Scholar
  33. 33.
    Santillan-Jimenez, E., Morgan, T., Lacny, J., et al., Fuel, 2013, vol. 103, pp. 1010–1017.CrossRefGoogle Scholar
  34. 34.
    Yasir, M., Azizan, M.T., Ramli, A., and Ameen, M., Procedia Eng., 2016, V. 148. P. 275–281.Google Scholar
  35. 35.
    Mikulec, J., Cvengroš, J., Joríková, L., et al., J. Cleaner Prod., 2010, vol. 18, no. 9, pp. 917–926.CrossRefGoogle Scholar
  36. 36.
    Mortensen, P.M., de Carvalho, H.W.P., Grunwaldt, J.-D., et al., J. Catal., 2015, vol. 328, pp. 208–215.CrossRefGoogle Scholar
  37. 37.
    Bui, V.N., Laurenti, D., Delichere, P., and Geantet, C., Appl. Catal., Ser. B, 2011, vol. 101, nos. 3–4, pp. 246–255.CrossRefGoogle Scholar
  38. 38.
    Duan, J., Han, J., Sun, H., et al., Catal. Commun., 2012, vol. 17, pp. 76–80.CrossRefGoogle Scholar
  39. 39.
    Kubička, D., Bejblová, M., and Vlk, J., Top. Catal., 2010, vol. 53, pp. 168–178.CrossRefGoogle Scholar
  40. 40.
    Wang, C., Liu, Q., Song, J., et al., Catal. Today, 2014, vol. 234, pp. 153–160.CrossRefGoogle Scholar
  41. 41.
    Liu, Q., Zuo, H., Zhang, Q., et al., Cuihua Xuebao/Chin. J. Catal., 2014, vol. 35, no. 5, pp. 748–756.CrossRefGoogle Scholar
  42. 42.
    Chen, N., Gong, S., and Qian, E.W., Appl. Catal., Ser. B, 2015, vols. 174–175, pp. 253–263.CrossRefGoogle Scholar
  43. 43.
    Liu, Q., Zuo, H., Wang, T., et al., Appl. Catal., Ser. A, 2013, vol. 468, pp. 68–74.CrossRefGoogle Scholar
  44. 44.
    Shahinuzzaman, M., Yaakob, Z., and Ahmed, Y., Renew. Sustain. Energy Rev., 2017, vol. 77, pp. 1375–1384.CrossRefGoogle Scholar
  45. 45.
    Ishihara, A., Fukui, N., Nasu, H., and Hashimoto, T., Fuel, 2014, vol. 134, pp. 611–617.CrossRefGoogle Scholar
  46. 46.
    Toba, M., Abe, Y., Kuramochi, H., et al., Catal. Today, 2011, vol. 164, no. 1, pp. 533–537.CrossRefGoogle Scholar
  47. 47.
    Chumachenko, Yu.A., Lavrenov, A.V., Buluchevskii, E.A., et al., Katal. Prom–sti., 2015, vol. 15, no. 4, pp. 49–64.Google Scholar
  48. 48.
    Mohammad, M., Kandaramath Hari, T., and Yaakob, Z., Renew. Sustain. Energy Rev., 2013, vol. 22, pp. 121–132.CrossRefGoogle Scholar
  49. 49.
    Patent WO 2004022674A1, Publ. 2004.Google Scholar
  50. 50.
    Patent EP 1396531B2, Publ. 2004.Google Scholar
  51. 51.
    Tom, N., Kalnes, T., Marker, T., et al., Biofuels Technol., 2008, Q4, pp. 7–11.Google Scholar
  52. 52.
    Kikhtyanin, O.V., Rubanov, A.E., Ayupov, A.B., and Echevsky, G.V., Fuel, 2010, vol. 89, pp. 3085–3092.CrossRefGoogle Scholar
  53. 53.
    Choi, I.H., Hwang, K.R., Han, J.S., et al., Fuel, 2015, vol. 158, pp. 98–104.CrossRefGoogle Scholar
  54. 54.
    Liu, S., Zhu, Q., Guan, Q., et al., Bioresource Technol., 2015, vol. 183, pp. 93–100.CrossRefGoogle Scholar
  55. 55.
    Wang, C., Tian, Z., and Wang, L., ChemSusChem, 2012, vol. 5, no. 10, pp. 1974–1983.CrossRefGoogle Scholar
  56. 56.
    Yurpalov, V.L., Drozdov, V.A., Karpova, T.R., and Lavrenov, A.V., Chem. Sustain. Develop., 2017, vol. 25, no. 1, pp. 107–113.Google Scholar
  57. 57.
    Khimicheskaya entsiklopediya (Chemical Encyclopedia), Knunyants, I.L., Ed., Moscow: Sov. Entsiklopediya, 1988, vol. 1, p. 421.Google Scholar
  58. 58.
    Shannon, R.D., Acta Crystallogr., Sect. A, 1976, vol. 32, pp. 751–767.CrossRefGoogle Scholar
  59. 59.
    Fedorova, E.D., Kazakov, M.O., Lavrenov, A.V., et al., Chem. Sustain. Develop., 2013, vol. 21, no. 1, pp. 107–113.Google Scholar
  60. 60.
    Karpova, T.R., Lavrenov, A.V., Buluchevsky, E.A., et al., Catal. Ind., 2014, vol. 6, no. 2, pp. 105–113.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • A. A. Nepomnyashchiy
    • 1
  • E. A. Buluchevskiy
    • 1
    • 2
  • A. V. Lavrenov
    • 1
  • V. L. Yurpalov
    • 1
  • T. I. Gulyaeva
    • 1
  • N. N. Leont’eva
    • 1
  • V. P. Talzi
    • 1
  1. 1.Institute of Hydrocarbons Processing, Siberian BranchRussian Academy of SciencesOmskRussia
  2. 2.Omsk F.M. Dostoevsky State UniversityOmskRussia

Personalised recommendations