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In Situ Formation of Al(Fe)/Cl Metal Chloride Complexes and Evaluation of Their Catalytic Properties in the Reaction of Ethylene Oligomerization

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Abstract

According to FT-IR and UV spectroscopic data, the interaction of the Al/Fe alloy with tert-butyl chloride results in that AlCl4–, Al2Cl7–, and FeCl2+ ion complexes, Fe3+ ions, and AlCl3 molecular form are produced in situ in the reaction medium. Ethylene was oligomerized in n-hexane on metal chloride complexes produced in situ from Al/Fe alloys and tert-butyl chloride.

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, ul. Neftezavodskaya 54, Omsk, 644040, Russia

    A. B. Arbuzov, E. N. Kudrya, M. V. Trenikhin & V. A. Drozdov

  2. Omsk Scientific Center; Siberian Branch, Russian Academy of Sciences, Omsk, 644024, Russia

    A. B. Arbuzov & M. V. Trenikhin

Authors
  1. A. B. Arbuzov
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  2. E. N. Kudrya
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  3. M. V. Trenikhin
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  4. V. A. Drozdov
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Correspondence to A. B. Arbuzov.

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Original Russian Text © A.B. Arbuzov, E.N. Kudrya, M.V. Trenikhin, V. A. Drozdov, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 11, pp. 1595−1599.

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Arbuzov, A.B., Kudrya, E.N., Trenikhin, M.V. et al. In Situ Formation of Al(Fe)/Cl Metal Chloride Complexes and Evaluation of Their Catalytic Properties in the Reaction of Ethylene Oligomerization. Russ J Appl Chem 90, 1926–1930 (2017). https://doi.org/10.1134/S1070427217120059

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  • DOI: https://doi.org/10.1134/S1070427217120059

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