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Kinetic Studies of Hydrodesulphurization of Dibenzothiophen on a Ni2P/MCM-41 Catalyst

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Abstract

The MCM-41 supported nickel phosphide catalyst was successfully prepared by impregnation of nickel phosphate precursors with MCM-41 support, followed by reduction of the precursors in hydrogen at 923 K. The as prepared Ni2P/MCM-41 catalyst was characterized by X-ray diffraction (XRD) and N2-adsorption specific surface area measurements (BET). The effects of reaction temperature, pressure, weight hourly space velocity (WHSV) and hydrogen to oil volume ratio (H2/Oil) on DBT HDS performance over Ni2P/MCM-41 were investigated with the model gasoline containing DBT. Finely, the kinetics for the DBT HDS over Ni2P/ MCM-41 catalyst was studied. The results showed that the active phase formed over Ni2P/M CM-41 catalyst was mainly Ni2P. The DBT conversion increased with increasing the reaction temperature, pressure, and H2/Oil ratio. However, increasing the WHSV would lead to a decrease in DBT conversion over Ni2P/ MCM-41 catalyst. A Langmuir–Hinshelwood model was used to analyze the kinetic data and to derive activation energy. In addition, take the effects of the pressure of H2 and H2/oil ratio into account, the modified kinetic model is also proposed: 1/(1–x)–1 = 10086.97e120.72RTp2.534H (H2/Oil)2.471WHSV–1.217.

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References

  1. Rupesh, S. and Deepak, K., Fuel, 2016, vol. 163, pp. 180–188.

    Article  CAS  Google Scholar 

  2. Ma, X. and Sun, L., Catal. Today, 2003, vol. 77, p. 107.

    Article  Google Scholar 

  3. Levy, R.E, Rappas, A.S., and Lee, F.M., J. Hydrocarbon Engng., 2002, vol. 7, p. 25.

    CAS  Google Scholar 

  4. Oyama, S.T., J. Catal., 2003, vol. 216, p. 343.

    Article  CAS  Google Scholar 

  5. Wang, X., Clark, P., and Oyama, S.T., J. Catal., 2002, vol. 208, p. 321.

    Article  CAS  Google Scholar 

  6. Shu, Y., Lee, Y.K., and Oyama, S.T., J. Catal., 2005, vol. 236, p. 112.

    Article  CAS  Google Scholar 

  7. Oyama, S.T., Wang, X., Lee, Y.K., and Chun, W.J., J. Catal., 2004, vol. 221, p. 263.

    Article  CAS  Google Scholar 

  8. Yang, S. and Liang, C., J. Catal., 2006, vol. 241, p. 465.

    Article  CAS  Google Scholar 

  9. Mangnus, P.J. and Eijsbouts, S., Appl. Catal., 1990, vol. 61, p. 99.

    Article  CAS  Google Scholar 

  10. Stinner, C., Tang, Z., Haouas, M., Weber, Th, and Prins, R., J. Catal., 2002, vol. 208, p. 456.

    Article  CAS  Google Scholar 

  11. Iwamoto, R. and Grimblot, J., Adv. Catal., 1999, vol. 44, p. 417.

    CAS  Google Scholar 

  12. Liu, L., Hong, L., Fuel, 2012, vol. 96, p. 348.

    Article  CAS  Google Scholar 

  13. Li, X., Zhang, Y.L., Wang, A., and Wang, Y., Catal. Commun., 2010, vol. 11, p. 1129.

    Article  CAS  Google Scholar 

  14. Song, H., Dai, M., Guo, Y., and Zhang, Y., Fuel Process. Technol. 2012, vol. 96, p. 228.

    Article  CAS  Google Scholar 

  15. Wang, K., Yang, B., Liu, Y., and Yi, C., Energy Fuels, 2009, vol. 23, p. 4209.

    Article  CAS  Google Scholar 

  16. Song, L., Li, W., Wang, G., Zhang, M., and Tao, K., Catal. Today, 2007, vol. 125, p. 137.

    Article  CAS  Google Scholar 

  17. Oyama, S.T. and Lee, Y.K., J. Catal., 2008, vol. 258, p. 393.

    Article  CAS  Google Scholar 

  18. Bandyopadyay, M. and Shiju, N., Catal. Commun. 2010, vol. 11, p. 660.

    Article  CAS  Google Scholar 

  19. Lee, Y.K., Shu, Y., and Oyama, S.T., Appl. Catal. A, 2007, vol. 322, p. 191.

    Article  CAS  Google Scholar 

  20. Wang, A., Ruan, L., and Teng, T., J. Catal., 2005, vol. 229, p. 320.

    Article  CAS  Google Scholar 

  21. Shun, Z., Li, X., and Wang, A., Catal. Today, 2013, vol. 211, pp. 126–130.

    Article  CAS  Google Scholar 

  22. Li, X., Shun, Z., and Wang, A., Catal.Commun., 2014, vol. 43, pp. 21–24.

    Article  CAS  Google Scholar 

  23. Song, H., Dai, M. and Wan, X., Appl. Catal. A, 2013, vol. 462, pp. 247–255.

    Article  CAS  Google Scholar 

  24. Oyama, S.T., Gott, T., and Asakura, K., J. Catal., 2009, vol. 268, pp. 209–222.

    Article  CAS  Google Scholar 

  25. Meléndez-Ortiz, H.I. and García-Cerda, L. A., Ceram. Int., 2012, vol. 38, pp. 6353–6358.

    Article  CAS  Google Scholar 

  26. Wang, A., Wang, Y., and Kabe, T., J. Catal., 2001, vol. 199, pp. 19–29.

    Article  CAS  Google Scholar 

  27. Deng, Z., Wang, T., and Wang, Z., Chem. Eng. Sci., 2010, vol. 65, pp. 480–486.

    Article  CAS  Google Scholar 

  28. Jarullah, A., Mujtaba, I., and Wood, A., Chem. Eng. Sci., 2011, vol. 66, pp. 859–871.

    Article  CAS  Google Scholar 

  29. Kordulis, C., Lappas, A., and Fountzoula, C., Appl. Catal. A, 2001, vol. 209, pp. 85–95.

    Article  CAS  Google Scholar 

  30. Wang, Y., Sun, Z., and Wang, A., Ind. Eng. Chem., 2004, vol. 43, pp. 2324–2329.

    Article  CAS  Google Scholar 

  31. Hamza, A. and Xiaoliang, M., Energy Fuels, 2017, vol. 31, pp. 831–838.

    Article  CAS  Google Scholar 

  32. Girgis, M. and Gates, B., Ind. Eng. Chem., 1991, vol. 30, p. 2021.

    Article  CAS  Google Scholar 

  33. Shafi, R. and Hutchings, G., Catal. Today., 2000, vol. 59, pp. 423–442.

    Article  CAS  Google Scholar 

  34. Rupesh, S. and Deepak, K., Fuel, 2016, vol. 163, pp. 180–188.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing, 163318, China

    N. Jiang, H. Song, X. W. Xu & F. Y. Zhang

  2. Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing, Heilongjing, 163318, China

    H. Song

  3. Department of Image College Mudanjiang, Medical University, Mudanjiang, Heilongjing, 157011, China

    H. L. Song

Authors
  1. N. Jiang
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  2. H. Song
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  3. H. L. Song
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  4. X. W. Xu
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  5. F. Y. Zhang
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Jiang, N., Song, H., Song, H.L. et al. Kinetic Studies of Hydrodesulphurization of Dibenzothiophen on a Ni2P/MCM-41 Catalyst. Russ J Appl Chem 90, 1883–1891 (2017). https://doi.org/10.1134/S1070427217110246

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  • DOI: https://doi.org/10.1134/S1070427217110246

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