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Synthesis of Decaborane by the Reaction of Sodium Undecaborate with Mild Organic Oxidants

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Abstract

New organic oxidants (aldehydes and ketones) allowing efficient synthesis of decaborane in a high yield via intermediate alkali metal salt were found. The sodium undecaborate oxidation process was refined, and new reaction stoichiometry was suggested.

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Authors and Affiliations

  1. State Research Institute of Chemistry and Technology of Organoelement Compounds, sh. Entuziastov 38, Moscow, 111123, Russia

    P. P. Belov, P. A. Storozhenko, N. S. Voloshina & M. G. Kuznetsova

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  1. P. P. Belov
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  2. P. A. Storozhenko
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  3. N. S. Voloshina
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  4. M. G. Kuznetsova
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Correspondence to P. P. Belov.

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Belov, P.P., Storozhenko, P.A., Voloshina, N.S. et al. Synthesis of Decaborane by the Reaction of Sodium Undecaborate with Mild Organic Oxidants. Russ J Appl Chem 90, 1804–1809 (2017). https://doi.org/10.1134/S107042721711012X

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  • DOI: https://doi.org/10.1134/S107042721711012X

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