Skip to main content
SpringerLink
Log in

Physicochemical Properties of Mesoporous Silicas Modified with Hydrazide and Amide Functional Groups

  • Inorganic Synthesis and Industrial Inorganic Chemistry
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Physicochemical properties of mesoporous silicas modified with hydrazide and amide functional groups were studied. It was found that the main properties of the sorbents under study, characterized by pKa1, are weakly pronounced. The replacement of the counter ion with a hydroxide occurs in a less alkaline medium, compared with monomer analogs. The sorbent modified with N', N'-dimethylhydrazide groups by the impregnation method has pKa2 = 11.78, which is indicative of a sufficient strength of bonding between the counter ion and the silica matrix. The temperature limits, heat effects, and decomposition stages of the sorbents were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Oi, H., Peng, Y., Gao, Q., and Zhang, Cn., Sensors, 2009, vol. 9, pp. 674–695.

    Article  CAS  Google Scholar 

  2. Zhong, L., Kaiyong, C., Beilu, Z., et. al., Prog. Chem., 2011, vol. 23, no. 11, pp. 2326–2338.

    Google Scholar 

  3. Lisichkin, G.V., Fadeev, A.Yu., Serdan, A.A., et al., Khimiya privitykh poverkhnostnykh soedinenii (Chemistry of Grafted Surface Compounds), Moscow: FIZMATLIT, 2003, pp. 38–56.

    Google Scholar 

  4. Oskotskaya, E.P., Basargin, H.H., Ignatov, D.E., and Rozovskii, Yu.G., Zavod. Lab., Diagn. Mater., 1999, vol. 65, no. 3, pp. 10–14.

    Google Scholar 

  5. Chibisov, A.N. and Chibisova, M.A., Zh. Tekh. Fiz., 2011, vol. 81, no. 4, pp. 138–140.

    Google Scholar 

  6. Batueva, T.D., Radushev, A.V., Shavkunov, S.P., et al., Khim. Tekhnol., 2014, vol. 15, no. 11, pp. 657–663.

    Google Scholar 

  7. Kholin, Yu.V., Kolichestvennyi fiziko-khimicheskii analiz kompleksoobrazovaniya v rastvorakh i na poverkhnosti khimicheski modifitsirovannykh kremnezemov: soderzhatel’nye modeli, matematicheskie metody i ikh prilozheniya (Quantitative Physicochemical Analysis of Complexation in Solutions and on the Surface of Chemically Modified Silicas: Conceptual Models, Mathematical Methods and Application of These), Kharkov: Folio, 2000, pp. 204–257.

    Google Scholar 

  8. Tessman, A.B., Ivanov, A.V., Vakshtein, M.S., and Nesterenko, P.N., Vestn. Mosk. Univ., Ser. 2, Khim., 2002, vol. 43, no. 1, pp. 13–16.

    Google Scholar 

  9. Neudachina, L.K., Pestov, A.V., Baranova, N.V., and Startsev, V.A., Anal. Kontrol, vol. 15, no. 2. 2011, pp. 238–250.

    Google Scholar 

  10. Pesavento, M., Biesuz, R., Gallorini, M., and Profimo, A., Anal. Chem., 1993, vol. 65, no. 3, pp. 2522–2527.

    Article  CAS  Google Scholar 

  11. Morlay, S., Cromer, M., Mouginot, Y., and Vittori, O., Talanta, 1998, vol. 45, no. 6, pp. 1177–1188.

    Article  CAS  PubMed  Google Scholar 

  12. Soldatov, V.S., Sosinovich, Z.I., Korshunova, T.A., and Mironova, T.V., React. Funct. Polym., 2004, vol. 58, no. 1, pp. 3–12.

    Article  CAS  Google Scholar 

  13. Radushev, A.V., Batueva, T.D., and Kataev, A.V., Sep. Sci. Technol., 2015, vol. 50, no. 4, pp. 512–519.

    Article  CAS  Google Scholar 

  14. Chelex 100 and Chelex 20 Chelating Ion Exchange Resin, Instruction Manual, Bio-Rad Laboratories, 2000 Alfred Nobel Dr., Hercules, CA94547.

Download references

Author information

Authors and Affiliations

  1. Institute of Technical Chemistry, Perm Federal Research Center, Ural Branch, Russian Academy of Sciences, Perm, Russia

    T. D. Batueva, N. B. Kondrashina, N. D. Kuz’micheva & T. G. Tiunova

  2. Perm State National Research University, ul. Bukireva 15, Perm, 614990, Russia

    M. G. Shcherban’

Authors
  1. T. D. Batueva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. B. Kondrashina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. D. Kuz’micheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. G. Tiunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. G. Shcherban’
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. D. Batueva.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Batueva, T.D., Kondrashina, N.B., Kuz’micheva, N.D. et al. Physicochemical Properties of Mesoporous Silicas Modified with Hydrazide and Amide Functional Groups. Russ J Appl Chem 90, 1746–1752 (2017). https://doi.org/10.1134/S1070427217110039

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427217110039

Search

Navigation