Skip to main content
SpringerLink
Log in

Hybrid Catalysts Based on Sulfated Zirconium Dioxide and H-beta Zeolite for Alkylation of Isobutane with Isobutylene

  • Various Technological Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Physicochemical properties of new hybrid catalysts based on sulfated zirconium oxide supported by zeolite of the Beta structural type were studied. The acid-base characteristics of the catalysts are determined by the amount of the supported component, the maximum concentration of Brønsted acid centers (277 μmol g–1) is reached upon deposition of 1.7 wt % sulfated zirconium oxide. The texture characteristics of the final catalyst are determined by the starting support. Tests of the catalysts in the reaction of isobutane alkylation with isobutylene demonstrated their advantage in selectivity and stability over the classical bulk sulfated zirconium oxide.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Vlasov, E.A., Catal. Lett., 2015, vol. 145, no. 9, pp. 1651–1659.

    Article  CAS  Google Scholar 

  2. Chen, A., J. Chinese Chem. Soc., 2010, no. 57, pp. 820–828.

    Article  CAS  Google Scholar 

  3. Busto, M., Fuel Process. Technol., 2012, vol. 104, pp. 128–135.

    Article  CAS  Google Scholar 

  4. Kustov, L.M., Russ. J. Phys. Chem. A, 2015, vol. 89, no. 11, pp. 2006–2021.

    Article  CAS  Google Scholar 

  5. Gizetdinova, A., J. Chem. Chem. Eng., 2014, vol. 8, no. 5, pp. 453–460.

    CAS  Google Scholar 

  6. US Patent 7 794 687 B2 (publ. 2010).

  7. Devyatkov, S.Y., Ind. Eng. Chem. Res., 2016, vol. 55, no. 23, pp. 57–64

    Article  Google Scholar 

  8. Emeis, C.A., J. Catal., 1993, vol. 14, no. 2, pp. 347–354.

    Article  Google Scholar 

  9. Gauna, M.R., Ceram.- Silik., 2015, vol. 50, no. 4, pp. 318–325.

    Google Scholar 

  10. Adebajo, M.O., Spectrochim. Acta, Part A, 2004, vol. 60, no. 4, pp. 791–799.

    Article  Google Scholar 

  11. Qi, X., J. Mater. Sci., 2008, vol. 43, no. 16, pp. 5626–5633.

    Article  CAS  Google Scholar 

  12. Sing, K.S.W., Assessment of Mesoporosity, Elsevier, 2014.

    Book  Google Scholar 

  13. Ye, F., Catal. Commun., 2009, vol. 10, pp. 2056–2059.

    Article  CAS  Google Scholar 

  14. Feller, A., J. Catal., 2003, vol. 216, nos. 1–2, pp. 313–323.

    Article  CAS  Google Scholar 

  15. Salinas, A.L., Appl. Catal., A, 2008, vol. 336, nos. 1–2, pp. 313–323.

    Google Scholar 

  16. Loenders, R., J. Catal., 1998, vol. 176, pp. 545–551.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State Technological Institute (Technical University), Moskovskii pr. 26, St. Petersburg, 190013, Russia

    E. A. Yuferova, S. Yu. Devyatkov, S. P. Fedorov, K. V. Semikin, D. A. Sladkovskii & N. V. Kuzichkin

Authors
  1. E. A. Yuferova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Yu. Devyatkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. P. Fedorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. V. Semikin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. A. Sladkovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. V. Kuzichkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. A. Yuferova.

Additional information

Original Russian Text © E.A. Yuferova, S.Yu. Devyatkov, S.P. Fedorov, K.V. Semikin, D.A. Sladkovskii, N.V. Kuzichkin, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 10, pp. 1323−1331.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yuferova, E.A., Devyatkov, S.Y., Fedorov, S.P. et al. Hybrid Catalysts Based on Sulfated Zirconium Dioxide and H-beta Zeolite for Alkylation of Isobutane with Isobutylene. Russ J Appl Chem 90, 1605–1613 (2017). https://doi.org/10.1134/S1070427217100081

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427217100081

Search

Navigation