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Hydrodesulfidation of the diesel fraction of pyrolytic fuel on polymetallic catalyst

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Abstract

Results are presented of a study of the liquid product formed in pyrolysis of automobile tires and fractions of this product. The diesel fraction of the pyrolytic liquid fuel was hydrodesulfided on a polymetallic catalyst. The results of the hydrodesulfidation in a flow-through laboratory installation in the temperature range 320–380°C at a hydrogen delivery rate of 6 L h–1 are shown. The experiment was performed during 1 h with preliminary activation in a flow of hydrogen for 2 h and raw material delivery rate of 4–16 mL h–1 on a polymetallic Al–Ni–V–Mo catalyst supported by γ-Al2O3. It was found that the degree of purification grows by 14% as the delivery rate is lowered from 16 to 8 mL h–1, and by 27% upon its decrease to 4 mL h–1. With temperature varied at the optimal raw material delivery rate of 4 mL h–1, the degree of purification also changes: the minimum degree of purification is observed at 320°C. The degree of purification grows by 7% as the process temperature is raised by 20°, and by 28% upon its increase by 40°.

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Authors and Affiliations

  1. West-Kazakhstan Innovation and Technology University, ul. Ikhsanova 44/1, Uralsk, Kazakhstan

    V. A. Burakhta & I. I. Gavrilina

  2. National Research Saratov State University named after N.G. Chernyshevsky, ul. Astrakhanskaya 83, Saratov, 410012, Russia

    R. I. Kuz’mina & R. A. Minasyan

Authors
  1. V. A. Burakhta
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  2. R. I. Kuz’mina
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  3. I. I. Gavrilina
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  4. R. A. Minasyan
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Correspondence to V. A. Burakhta.

Additional information

Original Russian Text © V.A. Burakhta, R.I. Kuz’mina, I.I. Gavrilina, R.A. Minasyan, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 8, pp. 1041−1046.

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Burakhta, V.A., Kuz’mina, R.I., Gavrilina, I.I. et al. Hydrodesulfidation of the diesel fraction of pyrolytic fuel on polymetallic catalyst. Russ J Appl Chem 90, 1273–1277 (2017). https://doi.org/10.1134/S1070427217080134

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  • DOI: https://doi.org/10.1134/S1070427217080134

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