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Electochemical characteristics of LiMn2O4/Li4Ti5O12 battery with conducting polymeric binder

  • Applied Electrochemistry and Metal Corrosion Protection
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Abstract

Lithium-ion battery based on LiMn2O4/Li4Ti5O12 materials was assembled for the first time. The cathode and anode of this battery are prepared with the aqueous combined binder poly-3,4-ethylenedioxythiophene: polystyrene sulfonate/carboxymethylcellulose (without polyvinylidene fluoride). The capacity of the LiMn2O4/Li4Ti5O12 battery was found to be 75 mA h g–1 at 0.1 C and 55 mA h g–1 at 1 C. A 95% capacity was retained after 100 charge-discharge cycles. The batteries demonstrated a high Coulombic efficiency close to 100%. Scanning electron microscopy demonstrated that using the conducting binder poly-3,4-ethylenedioxythiophene: polystyrene sulfonate/carboxymethylcellulose provides formation of dense compact layers of electrode materials with good adhesion to the substrate. The electrode structure remains maintained after 100 charge-discharge cycles.

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Authors and Affiliations

  1. Institute of Chemistry, St. Petersburg State University, Universitetskaya nab. 7/9, St. Petersburg, 199034, Russia

    S. N. Eliseeva, K. A. Vorob’eva, E. V. Shkreba, R. V. Apraksin & V. V. Kondrat’ev

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  1. S. N. Eliseeva
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  2. K. A. Vorob’eva
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  3. E. V. Shkreba
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  4. R. V. Apraksin
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  5. V. V. Kondrat’ev
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Correspondence to S. N. Eliseeva.

Additional information

Original Russian Text © S.N. Eliseeva, K.A. Vorob’eva, E.V. Shkreba, R.V. Apraksin, V.V. Kondrat’ev, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 8, pp. 997−1000.

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Eliseeva, S.N., Vorob’eva, K.A., Shkreba, E.V. et al. Electochemical characteristics of LiMn2O4/Li4Ti5O12 battery with conducting polymeric binder. Russ J Appl Chem 90, 1230–1233 (2017). https://doi.org/10.1134/S1070427217080067

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  • DOI: https://doi.org/10.1134/S1070427217080067

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