Skip to main content
SpringerLink
Log in

Effect of water vapor pressure on the phase composition of lithium monoaluminates formed in the interaction of aluminum hydroxide and lithium carbonate

  • Inorganic Synthesis and Industrial Inorganic Chemistry
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

It is shown that the partial water vapor pressure affects the phase composition of lithium monoaluminates formed when aluminum hydroxide (gibbsite) and lithium carbonate are heated in air, in the atmosphere of helium, and in a dynamic vacuum. When the mixture is heated to 800°C in an air atmosphere with partial water pressure of 1300 Pa, a nearly single-phase lithium monoaluminate α-LiAlO2 is formed. In the reaction in the atmosphere of helium, in which the partial water vapor pressure does not exceed 4 Pa, γ-LiAlO2 is formed together with α-LiAlO2, with the content of the former exceeding that produced in the reaction in air. When the mixture is heated under dynamic vacuum conditions with partial water vapor pressure lower than 0.1 Pa, mostly γ-LiAlO2 is formed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Molten Carbonate Fuel Cells EG&G Technical Services Inc., Fuel Cell Handbook (7th Ed.), 2004, National Energy Technology Laboratory, Morgantown, West Virginia, USA, 2004.

  2. Choi, H.J., Lee, J.J., Hyun, S.H., and Lim, H.C., Int. J. Hydrogen Energy, 2011, vol. 36, pp. 11048–11055.

    Article  CAS  Google Scholar 

  3. Choi, H.-J., Lee, J.J., Hyun, S.H., and Lim, H.C., Fuel Cells, 2009, no. 5, pp. 605–612.

    Article  Google Scholar 

  4. Gao, J., Shi, S., Xiao, R., and Li, H., Solid State Ionics, 2016, vol. 286, pp. 122–134.

    Article  CAS  Google Scholar 

  5. Isupov, V.P. and Eremina, N.V., Inorg. Mater., 2012, vol. 48, no. 9, pp. 918–924.

    Article  CAS  Google Scholar 

  6. Isupov, V.P., Trukhina, Ya.E., Eremina, N.V., et al., Inorg. Mater., 2016, vol. 52, no. 11, pp. 1189–1197.

    Article  CAS  Google Scholar 

  7. Candela, L. and Perlmutter, D.D., AlChE J., 1986, vol. 32, no. 9, pp. 1532–1545.

    Article  CAS  Google Scholar 

  8. Lee, S.K., Lee, S.B., Park, S.Y., et al., Phys. Rev. Lett., 2009, vol. 103, no. 9, pp. 095501–1–095501–4.

    Article  Google Scholar 

  9. Slade, R.C.T., Southern, J.C., and Thompson, I.M., J. Mater. Chem., 1991, vol. 1 (4), pp. 563–568.

    Article  CAS  Google Scholar 

  10. Sinitskii, A.S., Oleinikov, N.N., Murav’eva, N.N., and Tret’yakov, Yu.D., Inorg. Mater., 2003, vol. 39, no. 3, pp. 280–284.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid State Chemistry, and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, ul. Kutateladze 18, Novosibirsk, 630128, Russia

    V. P. Isupov, N. V. Bulina & I. A. Borodulina

Authors
  1. V. P. Isupov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. V. Bulina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Borodulina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. P. Isupov.

Additional information

Original Russian Text © V.P. Isupov, N.V. Bulina, I.A. Borodulina, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 8, pp. 986−991.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Isupov, V.P., Bulina, N.V. & Borodulina, I.A. Effect of water vapor pressure on the phase composition of lithium monoaluminates formed in the interaction of aluminum hydroxide and lithium carbonate. Russ J Appl Chem 90, 1219–1224 (2017). https://doi.org/10.1134/S1070427217080043

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427217080043

Search

Navigation