Abstract
Oxidation resistance of biodiesel synthesized by ester interchange of vegetable oil and animal fat triglycerides with methanol was studied. When stored under common conditions (in the dark at 20–25°С), the biodiesel is stable for no less than a year. However, the thermal oxidation resistance of biodiesel is low. The results obtained by different methods suggest that the processes occurring in the course of thermal oxidative degradation include not only radical-chain oxidation but also various condensation reactions showing no correlation with the former process. With this fact taken into account, additives enhancing the thermal oxidation resistance of biodiesel to the level of petroleum fuels containing no additives and no biodiesel were found among shielded phenols and aromatic amines. These additives prolong the shelf life of biodiesel fuel, which today is as short as 3 months, and allow the admissible concentration of biodiesel in mixtures with petroleum diesel fuel (7 vol %) to be increased.
References
Devyanin, S.N., Markov, V.A., and Semenov, V.G., Rastitel’nye masla i topliva an ikh osnove dlya dizel’nykh dvigatelei (Vegetable Oils and Fuels Based on Them for Diesel Engines), Moscow: Mosk. Gos. Agroinzhenernyi Univ., 2007.
Pramanik, T. and Tripathi, S., Neftegaz. Tekhnol., 2005, no. 6, pp. 65–70.
Bowman, M., Hilligoss, D., Rasmussen, S., and Thomas, R., Neftegaz. Tekhnol., 2006, no. 6, pp. 114–117.
Danilov, A.M., Petrol. Chem., 2015, vol. 55, no. 3, pp. 169–179.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.B. Shevchenko, A.M. Danilov, V.N. Kameneva, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 6, pp. 803−807.
Rights and permissions
About this article
Cite this article
Shevchenko, E.B., Danilov, A.M. & Kameneva, V.N. Oxidation resistance of biodiesel. Russ J Appl Chem 90, 1015–1018 (2017). https://doi.org/10.1134/S1070427217060246
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427217060246