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Effect of thermal treatment modes on ion-conducting properties of lithium-aluminum titanophosphate

  • Applied Electrochemistry and Metal Corrosion Protection
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Abstract

Dependence of the density of the Li1.3Al0.3Ti1.7(PO4)3 (LATP) ceramic on thermal treatment modes was studied. The conditions in which ceramic samples with density exceeding 90% are obtained were determined. It was found that the bulk ionic conductivity of LATP upon sintering at 1000°C for 2–6 h is (1.1–1.3) × 10–3 S cm–1 at 20°C, which corresponds to the maximum values for lithium-aluminum titanophosphate.

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References

  1. Aboulaich, A., Bouchet, R., Delaizir, G., et al., Adv. Energy Mater., 2011, vol. 1, pp. 179–183.

    Article  CAS  Google Scholar 

  2. US Patent 9 385 375 (publ. 2016).

  3. Breuer, S., Prutsch, D., Ma, Q., et al., J. Mater. Chem. A, 2015, vol. 3, pp. 21343–21350.

    Article  CAS  Google Scholar 

  4. Chang, C.-M., Lee, Y.I., Hong, S.-H., and Park, H.-M., J. Am. Ceram. Soc., 2005, vol. 88, no. 7, pp. 1803–1807.

    Article  CAS  Google Scholar 

  5. Perez-Estebanez, M., Isasi-Marín, J., Rivera-Calzada, A., et al. J. Alloys Compd., 2015, vol. 651, pp. 636–642.

    Article  CAS  Google Scholar 

  6. Bucharsky, E.C., Schell, K.G., Hintennach, A., and Hoffmann, M.J., Solid State Ionics, 2015, vol. 274, pp. 77–82.

    Article  CAS  Google Scholar 

  7. Wolfenstine, J., Allen, J.L., Sumner, J., and Sakamoto, J., Solid State Ionics, 2009, vol. 180, pp. 961–967.

    Article  CAS  Google Scholar 

  8. Aono, H., Sugimoto, E., Sadaoka, Y., et al., J. Electrochem. Soc., 1990, vol. 137, no. 4, pp. 1023–1027.

    Article  CAS  Google Scholar 

  9. Kunshina, G.B., Bocharova, I.V., and Ivanenko, V.I., Russ. J. Appl. Chem., 2016, vol. 89, no. 6, pp. 909–915.

    Article  CAS  Google Scholar 

  10. Cretin, M. and Fabry, P., J. Eur. Ceram. Soc., 1999, vol. 19, pp. 2931–2940.

    Article  CAS  Google Scholar 

  11. Xu, X., Wen, Z., Wu, X., et al., J. Am. Ceram. Soc., 2007, vol. 90, no. 9, pp. 2802–2806.

    Article  CAS  Google Scholar 

  12. Schroeder, M., Glatthaar, S., and Binder, J.R., Solid State Ionics, 2011, vol. 201, pp. 49–53.

    Article  CAS  Google Scholar 

  13. Kosova, N.V., Devyatkina, E.T., Stepanov, A.P., and Buzlukov, A.L., Ionics, 2008, vol. 14, pp. 303–311.

    Article  CAS  Google Scholar 

  14. Kotobuki, M. and Koishi, M., Ceram. Int., 2013, vol. 39, pp. 4645–4649.

    Article  CAS  Google Scholar 

  15. Svitan’ko, A.I., Novikova, S.A., Stenina, I.A., et al., Inorg. Mater., 2014, vol. 50, no. 3, pp. 273–279.

    Article  Google Scholar 

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Correspondence to G. B. Kunshina.

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Original Russian Text © G.B. Kunshina, I.V. Bocharova, V.I. Ivanenko, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 3, pp. 312−317.

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Kunshina, G.B., Bocharova, I.V. & Ivanenko, V.I. Effect of thermal treatment modes on ion-conducting properties of lithium-aluminum titanophosphate. Russ J Appl Chem 90, 374–379 (2017). https://doi.org/10.1134/S1070427217030089

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  • DOI: https://doi.org/10.1134/S1070427217030089

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