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Thermodynamic and kinetic stability of cerium(IV) complexes with a series of aminopolyacetic acids

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

The compositions, stability constants, and rate constants of intramolecular redox decomposition of cerium(IV) complexes with anions of aminoacetic (H2NCH2COOH), iminodiacetic [HN(CH2COOH)2], nitrilotriacetic [N(CH2COOH)3], ethylenediaminetetraacetic [(CH2COOH)2N(CH2)2N(CH2COOH)2], and hexamethylenediaminetetraacetic [(CH2COOH)2N(CH2)6N(CH2COOH)2] acids were determined by potentiometric, spectrophotometric, and kinetic methods at pH in the range 1.3−2.0 in perchlorate and nitrate media at an ionic strength I = 0.1 and a temperature of 298.15 K. Direct linear correlation between the logarithms of the stability constants of the complexes, log β101, and logarithms of the cumulative protonation constants, log В m+k (k = 1–2), of aminopolyacetic acid anions L m–, and inverse linear correlation between log β101 and logarithms of the rate constants of intramolecular redox decomposition of the complexonates [CeL]4–m (m = 1–4), log k n=1, were found.

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Authors and Affiliations

  1. Joint Institute for Nuclear Research, ul. Zholio Kuri 6, Dubna, Moscow oblast, 141980, Russia

    O. O. Voskresenskaya

  2. Tomsk State University, pr. Lenina 36, Tomsk, 634050, Russia

    N. A. Skorik

  3. Biisk Institute of Technology, ul. Trofimova 27, Biisk, Altai krai, 659305, Russia

    N. V. Stepanova

Authors
  1. O. O. Voskresenskaya
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  2. N. A. Skorik
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  3. N. V. Stepanova
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Correspondence to O. O. Voskresenskaya.

Additional information

Original Russian Text © O.O. Voskresenskaya, N.A. Skorik, N.V. Stepanova, 2016, published in Zhurnal Prikladnoi Khimii, 2016, Vol. 89, No. 11, pp. 1375−1385.

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Voskresenskaya, O.O., Skorik, N.A. & Stepanova, N.V. Thermodynamic and kinetic stability of cerium(IV) complexes with a series of aminopolyacetic acids. Russ J Appl Chem 89, 1747–1756 (2016). https://doi.org/10.1134/S1070427216110033

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  • DOI: https://doi.org/10.1134/S1070427216110033

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