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Bimetallic Co–Cu polyaniline composites: Structure and electrocatalytic activity

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Bimetallic Co–Cu polyaniline composites were produced by oxidative polymerization of aniline, with ammonium peroxydisulfate and hydrogen peroxide as oxidizing agents. Co(II) and Cu(II) chlorides were introduced into the polymer by the in situ method. It was found that the phase constitution of the composites is affected by their synthesis conditions and content of both metals in them. The electrocatalytic activity of the composites in the electrohydrogenation of p-nitroaniline in an aqueous-alcoholic-alkaline medium of the catholyte was studied and found to exceed that of composites synthesized with the use of H2O2 and evaporation of the solvent.

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Authors and Affiliations

  1. Institute of Organic Synthesis and Coal Chemistry of the Republic of Kazakhstan, ul. Alikhanova 1, Karaganda, 100008, Kazakhstan

    N. M. Ivanova, E. A. Soboleva & Ya. A. Visurkhanova

Authors
  1. N. M. Ivanova
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  2. E. A. Soboleva
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  3. Ya. A. Visurkhanova
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Correspondence to N. M. Ivanova.

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Original Russian Text © N.M. Ivanova, E.A. Soboleva, Ya.A. Visurkhanova, 2016, published in Zhurnal Prikladnoi Khimii, 2016, Vol. 89, No. 7, pp. 877−886.

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Ivanova, N.M., Soboleva, E.A. & Visurkhanova, Y.A. Bimetallic Co–Cu polyaniline composites: Structure and electrocatalytic activity. Russ J Appl Chem 89, 1072–1081 (2016). https://doi.org/10.1134/S1070427216070053

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  • DOI: https://doi.org/10.1134/S1070427216070053

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