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Density evolution of the energy-rich compound furazano[3,4-e]tetrazine-4,6-dioxide as stability indicator during prolonged storage

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Pycnometric method, powder X-ray diffraction analysis, and IR spectroscopy were used to study the fundamental aspects of how the density of energy-rich compound furazano[3,4-e]tetrazine-4,6-dioxide varies during its prolonged storage. It was shown that the density grows during the first stage with length of up to 14 days due to the recrystallization. In further storage during eight years, the density gradually falls due to the buildup of stresses in the crystal lattice, created by thermal decomposition products. The degree of decomposition at 22°C during 8 years, evaluated by extrapolation of the Arrhenius dependence, is 0.24%. The observed decrease in the density is attributed to the anomalously weak hampering effect of the crystal lattice.

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References

  1. Churakov, A.M., Ioffe, S.L., and Tartakovsky, V.A., Mendeleev Commun., 1995, vol. 5, no. 6, pp. 227–228.

    Article  Google Scholar 

  2. Zelenov, V.P., Lobanova, A.A., Lukshenko, N.V., et al., Russ. Chem. Bull. Int. Ed., 2008, vol. 57, no. 7, pp. 1384–1389.

    Article  CAS  Google Scholar 

  3. Berlyand, L.V., Chukanov, N.V., and Dubovitsky, V.A., Chem. Phys. Lett., 1991, vol. 181, no. 5, pp. 450–454.

    Article  CAS  Google Scholar 

  4. Nedel’ko, V.V., Zakharov, V.V., Korsunskii, B.L., et al., Russ. J. Phys. Chem. B, 2013, vol. 7, no. 2, pp. 113–117.

    Article  Google Scholar 

  5. Burov. Yu.M., Dubovitskii, F.I., Manelis, G.B., and Nazin, G.M., Dokl. Ross. Akad. Nauk, 1998, vol. 359, no. 5, pp. 641–643.

    CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    N. V. Chukanov, G. V. Shilov, A. V. Shastin, V. V. Nedelko, S. A. Vozchikova & B. L. Korsunskii

  2. Altai Federal Research-and-Production Center, ul. Sotsialisticheskaya 1, Biisk, Altai krai, 659322, Russia

    I. P. Kalmykov

Authors
  1. N. V. Chukanov
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  2. I. P. Kalmykov
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  3. G. V. Shilov
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  4. A. V. Shastin
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  5. V. V. Nedelko
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  6. S. A. Vozchikova
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  7. B. L. Korsunskii
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Corresponding author

Correspondence to N. V. Chukanov.

Additional information

Original Russian Text © N.V. Chukanov, I.P. Kalmykov, G.V. Shilov, A.V. Shastin, V.V. Nedelko, S.A. Vozchikova, B.L. Korsunskii, 2016, published in Zhurnal Prikladnoi Khimii, 2016, Vol. 89, No. 4, pp. 449−452.

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Chukanov, N.V., Kalmykov, I.P., Shilov, G.V. et al. Density evolution of the energy-rich compound furazano[3,4-e]tetrazine-4,6-dioxide as stability indicator during prolonged storage. Russ J Appl Chem 89, 566–569 (2016). https://doi.org/10.1134/S1070427216040078

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  • DOI: https://doi.org/10.1134/S1070427216040078

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