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New composite catalysts for the synthesis of acetonitrile from ethanol and ammonia, prepared using calcium aluminates (Talyum)

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Abstract

Experiments on direct synthesis of acetonitrile from ethanol, ammonia, and hydrogen at 513–573 K in the presence of new Cu-, Cu–Zn–(Zr)-, and Cu–Mg-containing composite catalysts prepared using calcium aluminates (Talyum, technical-grade calcium aluminate) were performed The following results were reached: ethanol conversion 96.0–99.0%, selectivity with respect to acetonitrile 99.0%, and acetonitrile output exceeding the reported level by a factor of 1.2–1.4. The new technology can be implemented in industry.

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References

  1. Yining Zhang, Yuecheng Zhang, Cheng Feng, et al., Catal. Commun., 2009, vol. 10, no. 10, pp. 1454–1458.

    Article  Google Scholar 

  2. Di Zhang, Yuecheng Zhang, Yanlong Wen, et al., Chem. Eng. Res. Des., 2011, vol. 89, pp. 2147–2152.

    Article  Google Scholar 

  3. Cheng Feng, Yuecheng Zhang, Yining Zhang, et al., Catal. Lett., 2011, vol. 141, pp. 168–177.

    Article  Google Scholar 

  4. Yunfeng Hu, Jinpeng Cao, Jun Deng, et al., Reac. Kinet. Mech. Cat., 2012, vol. 106, pp. 127–139.

    Article  Google Scholar 

  5. Golosman, E.Z., Kinet. Catal., 2001, vol. 42, no. 3, pp. 344–353.

    Article  CAS  Google Scholar 

  6. Belov, V.V., Markov, V.I., Sova, S.B., et al., Khim. Tekhnol., 2012, no. 9, pp. 534–542.

    Google Scholar 

  7. Golosman, E.Z., Nechugovskii, A.I., Kreindel’, A.I., et al., Khim. Prom–st’., 1999, no. 1, pp. 55–60.

    Google Scholar 

  8. Golosman, E.Z. and Nechugovskii, A.I., Khim. Prom–st’., 1994, no. 4, pp. 29–35.

    Google Scholar 

  9. Ukrainian Patent 92433, Publ. 2010.

  10. Ukrainian Patent 92476, Publ. 2014.

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Authors and Affiliations

  1. Ukrainian State University of Chemical Technology, pr. Gagarina 8, Dnepropetrovsk, 49005, Ukraine

    V. V. Belov, V. I. Markov & S. B. Sova

  2. OOO NIAP-Katalizator, Novomoskovsk, Tula oblast, Russia

    E. Z. Golosman & A. I. Nechugovskii

Authors
  1. V. V. Belov
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  2. V. I. Markov
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  3. S. B. Sova
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  4. E. Z. Golosman
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  5. A. I. Nechugovskii
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Corresponding author

Correspondence to V. V. Belov.

Additional information

Original Russian Text © V.V. Belov, V.I. Markov, S.B. Sova, E.Z. Golosman, A.I. Nechugovskii, 2016, published in Zhurnal Prikladnoi Khimii, 2016, Vol. 89, No. 3, pp. 362−369.

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Belov, V.V., Markov, V.I., Sova, S.B. et al. New composite catalysts for the synthesis of acetonitrile from ethanol and ammonia, prepared using calcium aluminates (Talyum). Russ J Appl Chem 89, 414–420 (2016). https://doi.org/10.1134/S1070427216030113

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  • DOI: https://doi.org/10.1134/S1070427216030113

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