Abstract
Crystalline phases of polyacrylamide titanium tungstophosphate composite material has been synthesized via sol–gel method. The properties of its were determined using different technique. The ion-exchange capacities of the hybrid material for Cs+, Co2+ and Eu3+ ions it was found that 6.22, 2.76 and 1.38 mequiv. g–1 respectively. The material was found that highly selective for Eu3+ and the selectivity sequence for sorption of Cs+, Co2+ and Eu3+ ions on polyacrylamide titanium tungstophosphate was found that; Eu3+ > Cs+ > Co2+. Thermodynamic parameters have been calculated for the studied ions showing that the overall adsorption process is spontaneous and endothermic. The experimental isotherm data were analyzed using the Langmuir and Freundlich models.
Similar content being viewed by others
References
IAEA., Tech. Rep. Ser., no. 408, 2002; IAEA., Tech. Re. Ser., no. 248, 1985
Kemp, R.V., Bennett, D.G., and White, M.J., Env. Int., 2006, vol. 32(8), pp. 1021–1032.
El-Naggar, I.M., Ibrahim, G.M., El-Kady, E.A., and Hegazy, E.A., Desalination, 2009, vol. 237, pp. 147–154.
El-Naggar, I.M., Mowafy, E.A., Abdel-Galil, E.A., and El-Shahat, M.F., Global J. Phys. Chem., 2010, vol. 1(1), pp. 91–106.
El-Naggar, I.M., Zakaria, E.S., El-Kenany, W.M., and El-Shahat, M.F., Radiochem., 2014, vol. 56(1), pp. 86–91.
Khan, A.A., and Alam, M.M., Mat. Res. Bull., 2005, vol. 40, pp. 289–305.
Khan, A.A. Inamuddin, Reac. & Func. Polymers, 2006, vol. 66, pp. 1649–1663.
Khan, A.A. and Alam, M.M., Reac. & Func. Polymers, 2003, vol. 55, pp. 277–290.
Khan, A.A. and Alam, M.M., Anal. Chimica Acta, 2004, vol. 504, pp. 253–264.
Niwas, R., Khan, A.A., and Varshney, K.G., Colloids & Surfaces A, 1999, vol. 150, pp. 7–14.
Nabi, S.A., Ganai, S.A., and Khan, A.M., J. Surfactants & Detergents, 2008, vol. 11, pp. 207–213.
El-Said, H., El-Amir, M.A., Abdel-Aziz, H.M., and Siyam, T., Radiochem., 2012, vol. 54(3), pp. 269–273.
Rao, C.N.R., Chemical Applications of Infrared Spectroscopy, New York: Academic Press, 1963.
Murugan, R., Mohan, S., and Bigotto, A., J. Korean Phys. Soc., 1998, vol. 32(4), pp. 505–512.
Nabi, S.A., Naushad, M., and Inamuddin. J. Hazardous Mat., 2007, vol. 142, pp. 404–411.
Vesely, V. and Pekarek, V., J. Inorg. & Nuclear Chem., 1963, 25, pp. 697–709.
Nabi, S.A. and Siddiqui, Z.M., Bull. Chem. Soc. Japan, 1999, vol. 58, pp. 724–730.
El-Naggar, I.M. Zakaria, E.S., Ali, I.M., Khalil, M., and El-Shahat, M.F., Arabian J. Chem., 2012, vol. 5, pp. 109–119.
Duval, C., Inorganic Thermogravimetric Analysis, Amsterdam: Elsevier, 1963.
El-Kamash, A.M., El-Gammal, B., and El-Sayed, A.A., J. Hazardous Mat., 2007, vol. 141, pp. 719–728.
Siddiqui, Z.M. and Pathania, D., J. Chromatogr. A, 2003, vol. 987, pp. 147–158.
Alberti, G., Torracca, E., and Conte, A., J. Inorganic and Nuclear Chem., 1966. vol. 28, pp. 607–613.
Rawat, J.P. and Singh, J.P., Can. J. Chem., 1976, vol. 54, pp. 2534–2539.
Nabi, S.A., Islam, A., and Rahman, N., Annales de Chimie Sci. des Materiaux, 1997, vol. 22, pp. 463–473.
Borgo, C.A., Lazarin, A.M., Kholin, Y.V., Landers, R., and Gushikem, Y., J. Brazilian Chem. Soc., 2004, vol. 15, pp. 50–57.
Aly, H.F., Zakaria, E.S., Shady, S.A., and El-Naggar, I.M., J. Radioanal. & Nuclear Chem., 1999, vol. 241, no. 2, pp. 331–336.
El-Naggar, I.M., Zakaria, E.S., Shady, S.A., and Aly, H.F., Solid State Ionics, 1999, vol. 122, pp. 65–70.
Lahiria, S., Roya, K., Bhattacharyab, S., Majic, S., and Basuc, S., Appl. Radiation & Isotopes, 2005, vol. 63, pp. 293–297.
El-Gammal, B. and Shady, S.A., Colloids & Surfaces A, 2006, vol. 287, pp. 132–138.
El-Naggar, I.M. and Abou-Mesalam, M.M., J. Hazardous Mat., 2007, vol. 149, pp. 686–692.
Ali, I.M., Zakaria, E.S., Ibrahim, M.M., and El-Naggar, I.M., Polyhedron, 2008, vol. 27, pp. 429–439.
Abdel-Galil, E.A., Chemical Studies and Sorption Behavior of Some Hazardous Metal Ions on Polyacrylamide Stannic(IV) Molybdophosphate as Organic-Inorganic Composite Cation Exchange, Ph.D. Thesis, Chem. Department, Faculty of Science, Ain Shams University.
Abou-Mesalam, M.M. and El-Naggar, I.M., J. Radioanal & Nuclear Chem., 2009, vol. 279, pp. 333–340.
El-Naggar, I.M., Mowafy, E.A., Abdel-Galil, E.A., and Ghonaim, A.Kh., Arabian J. Nuclear Sci. Appl., 2008, vol. 41, no. 3, pp. 1–14.
Abou-Mesalam, M.M., and Shady, S.A., Arabian J. Nuclear Sci. Application, 2004, vol. 37, pp. 101–111.
El-Naggar, I.M., Zakaria, E.S., and Aly, H.F., Reac. & Func. Polymers, 1996, vol. 28, pp. 215–220.
El-Naggar, I.M. and Abou-Mesalam, M.M. Arabian J. Nuclear Sci. Appl., 2006, vol. 39, pp. 50–60.
Zakaria, E.S., Ali, I.M., and El-Naggar, I.M., J. Radioanal. & Nuclear Chem., 2004, 261, pp. 689–696.
El-Shahat, H.F., Saad, E.A., Burham, N., and El-Naggar, I.M., Microchem. J., 1998, vol. 60, pp. 95–100.
Moloukhia, H., J. Rad. Res. & Appl. Sci., 2010, vol. 3(2), pp. 343–356.
Khan, A.A., Khan, A., Talanta, 2007, vol. 72, pp. 699–710.
Nabi, S.A. and Naushad, M. Colloids & Surfaces A, 2008, vol. 316, pp. 217–225.
Hameed, B.H., Ahmad, A.L., and Latiff, K.N.A., Dyes & Pigments, 2007, vol. 75, pp. 143–149.
Clark, A., Theory of Adsorption and Catalysis, New York: Academic Press, 1970.
Langmuir, I., J. Am. Chem. Soc., 1916, vol. 38, pp. 2221–2295.
Altin, O., Ozbelge, H.O., and Dogu, T., J. Colloid & Int. Sci., 2008, vol. 198, pp. 130–140.
Abd El-Rahman, K.M., El-Kamash, A.M., El-Sourougy, M.R., and Abdel-Moniem, N.M., J. Radioanal. & Nuclear Chem., 2006, vol. 268(2), pp. 221–230.
Argun, M.E., Dursun, S., Ozdemir, C., and Karatas, M., J. Hazardous Mat., 2007, vol. 141, pp. 77–85.
Freundlich, H.M.F., Zeitschrift fur Physikalische Chemie, 1906, vol. 57, p. 385.
El-Aryan H., Arabian J. Chem., 2014, vol. 5, pp. 109–119.
Author information
Authors and Affiliations
Corresponding author
Additional information
The text was submitted by the authors in English.
Rights and permissions
About this article
Cite this article
Abdel-Galil, E.A., Sharaf El-Deen, G.E., El-Aryan, Y.F. et al. Preparation of hybrid ion exchanger based on acrylamide for sorption of some toxic metal ions from aqueous waste solutions. Russ J Appl Chem 89, 467–479 (2016). https://doi.org/10.1134/S10704272160030198
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S10704272160030198