Skip to main content
SpringerLink
Log in

Optimization of process parameters of γ-polyoxymethylene synthesis

  • Macromolecular Compounds and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Two procedures for γ-polyoxymethylene production are considered: the existing commercial procedure and high-efficiency perspective procedure, differing in the chain-transfer agents and catalysts used. Mathematical models of the dependences of the yield and weight-average particle size of γ-polyoxymethylene on the synthesis process parameters for the commercial and perspective technologies are constructed using the method of optimum experiment design. The mathematical models were used for determining the optimum synthesis parameters allowing preparation of γ-polyoxymethylene with the weight-average particle size d ≤ 14 μm in maximal yields.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Auerbuch, F. and Barcell, H., Studien über Formaldehyde— die festen Polymeren des Formaldehyds, Berlin: Springer, 1907, pp. 26–34.

    Google Scholar 

  2. RF Patent 2244723, Publ. 2005.

  3. RF Patent 2412953, Publ. 2011.

  4. RF Patent 2176650, Publ. 2001.

  5. RF Patent 2471814, Publ. 2013.

  6. Sautin, S.N., Planirovanie eksperimenta v khimii i khimicheskoi tekhnologii (Design of Experiments in Chemistry and Chemical Technology), Leningrad: Khimiya, 1975.

    Google Scholar 

  7. Fedoseev, A.M. and Isakov, N.A., Vestn. Permsk. Gos. Tekh. Univ., Ser.: Aerokosm. Tekh., 2006, no. 25, pp. 115–120.

    Google Scholar 

  8. Boyarinov, A.I. and Kafarov, V.V., Metody optimizatsii v khimicheskoi tekhknologii (Optimization Methods in Chemical Technology), Moscow: Khimiya, 1969.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Research Institute of Polymeric Materials, ul. Chistopol’skaya 16, Perm, 614113, Russia

    V. M. Zinov’ev & O. A. Gladkova

  2. Perm National Research Polytechnic University, Komsomolskii pr. 29, Perm, 614990, Russia

    V. M. Zinov’ev, O. A. Gladkova & A. M. Fedoseev

Authors
  1. V. M. Zinov’ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. A. Gladkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. M. Fedoseev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. M. Zinov’ev.

Additional information

Original Russian Text © V.M. Zinov’ev, O.A. Gladkova, A.M. Fedoseev, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 10, pp. 1491−1497.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zinov’ev, V.M., Gladkova, O.A. & Fedoseev, A.M. Optimization of process parameters of γ-polyoxymethylene synthesis. Russ J Appl Chem 88, 1673–1678 (2015). https://doi.org/10.1134/S1070427215100195

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427215100195

Keywords

Search

Navigation