Abstract
A block copolymer based on N-isopropylacrylamide and glycidyl methacrylate was synthesized by atom transfer radical polymerization with the aim of modification of the aluminum surface by the “grafting to” method. The copolymer structure was proved by elemental analysis, gel permeation chromatography, and differential scanning calorimetry. The grafting of the block copolymer to the aluminum surface allows control of its wettability at repeated temperature changes.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Khimiya privitykh poverkhnostnykh soedinenii (Chemistry of Grafted Surface Compounds), Lisichkin, G.V., Ed., Moscow: Fizmatlit, 2003.
Boinovich, L.B. and Emelyanenko, A.M., Russ. Chem. Rev., 2008, vol. 77, no. 7, pp. 583–600.
Polymer Brushes, Advincula, R.C., Brittain, W.J., Caster, K.C., and Rühe, J., Eds., Weinheim: Wiley-VCH, 2004.
Demirci, S. and Caykara, T., J. Polym. Sci. A: Polym. Chem., 2012, vol. 50, pp. 2999–3007.
Strozyk, M.S., Chanana, M., Pastoriza-Santos, I., et al., Adv. Funct. Mater., 2012, vol. 22, pp. 1436–1444.
Kim, D.J., Heo, J., Kim, K.S., and Choi, I.S., Macromol. Rapid Commun., 2003, vol. 24, pp. 517–521.
Bryuzgin, E.V., Klimov, V.V., Zaytsev, S.D., et al., Russ. Chem. Bull., 2014, vol. 63, no. 7, pp. 1610–1614.
Bryuzgin, E., Navrotskiy, A., Hyakutake, T., et al., J. Nanostruct. Polym. Nanocomp., 2013, vol. 9, pp. 97–101.
Bryuzgin, E.V., Takahashi, K., Navrotskiy, A.V., et al., Protect. Met. Phys. Chem. Surf. 2012. Vol. 48. P. 184–190.
Fristrup, C.J., Jankova, K., and Hvilsted, S., Soft Matter, 2009, vol. 5, pp. 4623–4634.
Minko, S., J. Macromol. Sci., Part C: Polym. Rev., 2006, vol. 46, pp. 397–420.
Luzinov, I., Minko, S., and Tsukruk, V.V., Prog. Polym. Sci., 2004, vol. 29, pp. 635–698.
Liu, Y., Klep, V., Zdyrko, B., and Luzinov, I., Langmuir, 2004, vol. 20, pp. 6710–6718.
Practical Surface Analysis: by Auger and X-ray Photoelectron Spectroscopy, Briggs, D. and Seah, M.P., Eds., Chichester: Wiley, 1983.
Brizzolara, R.A., Surf. Interface Anal., 2002, vol. 33, pp. 351–360.
Massey, S., Adnot, A., Rje, A., and Roy, D., Express Polym. Lett., 2007, vol. 1, no, 8, pp. 506–511.
Hui, C.H., Pietrasik, J., Schmitt, M., et al., Chem. Mater., 2014, vol. 26, no. 1, pp. 745–762.
Zdyrko, B. and Luzinov, I., Macromol. Rapid Commun., 2011, vol. 32, pp. 859–869.
Marshall, N., Sontag, S.K., and Locklin, J., Chem. Commun., 2011, vol. 47, pp. 5681–5689.
Polymer Handbook, Brandrup, J., Immergut, E.H., and Grulke, E.A., Eds., New York: Wiley, 1999, 4th ed.
Djouani, F., Herbst, F., Chehimi, M., and Benzarti, K., Construct. Build. Mater., 2011, vol. 25, pp. 424–431.
Stimuli-Responsive Materials, Urban, M.W., Ed., Weinheim: Wiley-VCH, 2011.
Sun, T., Wang, G., Feng, L., et al., Angew. Chem. Int. Ed., 2004, vol. 43, pp. 357–360.
Fu, Q., Rao, G.V.R., Basame, S.B., et al., J. Am. Chem. Soc., 2004, vol. 126, pp. 8904–8905.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.V. Bryuzgin, V.V. Klimov, E.I. Bologova, I.D. Grishin, S.D. Zaitsev, A.V. Navrotskii, I.A. Novakov, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 3, pp. 506–511.
Rights and permissions
About this article
Cite this article
Bryuzgin, E.V., Klimov, V.V., Bologova, E.I. et al. Control of the wettability of the aluminum surface by its modification with grafted block copolymers based on N-isopropylacrylamide. Russ J Appl Chem 88, 510–515 (2015). https://doi.org/10.1134/S1070427215030222
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427215030222