Skip to main content
SpringerLink
Log in

New adsorbents and acid-base catalysts based on binder-free granulated zeolites of LTA and FAU types

  • Physicochemical Studies of Systems and Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

It is demonstrated that catalysts promising for deep drying and purification to remove sulfur compounds and CO2 from gaseous and liquid media of various compositions, e.g., natural gas and low-molecular olefins, have been developed in the last 10–15 years on the basis of binder-free granulated zeolites of types A and X. Type-X granulated zeolites in various cation-decationated forms without binders are promising materials as catalysts for processing of hydrocarbon raw materials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Breck, D.W., Zeolite Molecular Sieves, New York: Wiley-Interscience, 1974.

    Google Scholar 

  2. Zhdanov, S.P., Khvoshchev, S.S., and Smulevich, N.N., Sinteticheskie tseolity (Synthetic Zeolites), Moscow: Khimiya, 1981.

    Google Scholar 

  3. Movsumzade, E.M., Prirodnye i sinteticheskie tseolity, ikh poluchenie i primenenie (Natural and Synthetic Zeoplites, Their Synthesis and Application), Ufa: Reaktiv, 2000.

    Google Scholar 

  4. Shumyatskii, Yu.I., Promyshlennye adsorbtsionnye protsessy (Industrial Adsorption Processes), Moscow: Kolos, 2009.

    Google Scholar 

  5. US Patent no. 6,106,593.

  6. US Patent no. 6,406,519.

  7. Isakov, Ya.I., Neftekhimiya, 1998, vol. 38, pp. 404–438.

    CAS  Google Scholar 

  8. Corma, C. and Martnez, A., Studies Surf. Sci. Catal., 2005, vol. 157, pp. 337–366.

    Article  CAS  Google Scholar 

  9. Martinez, A. and Corma, C., Coord. Chem. Rev., 2011, vol. 255(13–14), pp. 1558–1580.

    Article  CAS  Google Scholar 

  10. Čejka, J., Centi, G., Perez-Pariente, J., and Roth, W.J., Catal. Today, 2012, vol. 179(1), pp. 2–15.

    Article  Google Scholar 

  11. Mirskii, Ya.V. and Dorogochinskii, A.Z., Doklady Akad. Nauk SSSR, 1966, vol. 170, no. 3, pp. 644–647.

    CAS  Google Scholar 

  12. RF Patent no. 2146223.

  13. US Patent no. 6,478,854.

  14. Ishchenko, L.M., Meged’, N.F., Mirskii, Ya.V., and Mityaeva, L.P., Tseolitnye katalizatory i adsorbenty: Sbornik trudov GrozNII (Zeolite Catalysts and Adsorbents: Coll. of Works of Groznyi Research Inst.) Moscow: TsNIITEneftekhim, 1978, issue 33, pp. 37–45.

    Google Scholar 

  15. US Patent no. 3,709,979.

  16. Travkina, O.S., Natural Aluminosilicates of Kaolinite Structure in Syntheses of High-Efficiency Zeolite Adsorbents and Catalysts), Cand. Sci. Dissertation, Ufa, 2010.

    Google Scholar 

  17. Pavlov, M.L., Travkina, O.S., and Kutepov, B.I., Kataliz Prom-sti, 2011, no. 4, pp. 42–51.

    Google Scholar 

  18. RF Patent no. 2412903.

  19. Pavlov, M.L., Basimova, R.A., Pavlova, I.N., and Kutepov, B.I., Petrol. Chem., 2009, vol. 49, no. 1, pp. 36–41.

    Article  Google Scholar 

  20. Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Fundamentals of Adsorption Technology), Moscow: Khimiya, 1984.

    Google Scholar 

  21. Kutepov, B.I., Pavlov, M.L., Pavlova, I.N., and Travkina, O.S., Khim. Tekhnol., 2009, no. 3, pp. 132–136.

    Google Scholar 

  22. Pavlova, I.N., Ilibaev, R.S., and Travkina, O.S., Russ. J. Appl. Chem., 2011, vol. 84, no. 5, pp. 782–785.

    Article  CAS  Google Scholar 

  23. Pavlova, I.N., Kutepov, B.I., and Ilibaev, R.S., Khim. Tekhnol., 2012, no. 11, pp. 48–53.

    Google Scholar 

  24. Ilibaev, R.S., Drying and Purification of Natural Gas To Remove Admixtures of Hydrogen Sulfide and Carbon Dioxide on Exchange Forms of Granulated Binder Free A and X Zeolites, Cand. Sci. Dissertation, Ufa, 2012.

    Google Scholar 

  25. Pavlova, I.N., Kutepov, B.I., and Travkina, O.S., Petrol. Chem., 2013, vol. 53, no. 2, pp. 102–109.

    Article  CAS  Google Scholar 

  26. Rabo, J.A., Zeolite Chemistry and Catalysis, Amer. Chemical Society, 1976.

    Google Scholar 

  27. Mishin, I.V., Klyachko, A.L., Brueva, T.R., et al., Kinet. Kataliz, 1993, vol. 34, no. 5, pp. 929–935.

    CAS  Google Scholar 

  28. Noda, T., Suzuki, K., Katada, N., and Niwa, M., J. Catal., 2008, vol. 259, pp. 203–210.

    Article  CAS  Google Scholar 

  29. Basimova, R.A., Liquid-Phase Disproportionation of Diethylbenzenes and Benzene under the Action of Zeolitecontaining Catalysts, Cand. Sci. Dissertation, Ufa, 2009.

    Google Scholar 

  30. Khazipova, A.N., Pavlova, I.N., Grigor’eva, N.G., et al., Tekhnol. Neorgan. Veshch. Mater., 2012, no. 1, pp. 5–10.

    Google Scholar 

  31. RF Patent no. 2483052.

  32. Grigor’eva, N.G., Bubennov, S.V., and Kutepov, B.I., Kataliz Prom-sti, 2011, no. 6, pp. 14–21.

    Google Scholar 

  33. Pavlov, M.L., Basimova, R.A., and Kutepov, B.I., Rossiski kongress po katalizu “ROSKATALIZ” (Russian Congress on Catalysis “ROSKATALIZ”), Moscow, 2011, vol. 1, p. 127.

    Google Scholar 

  34. Khusnutdinov, R.I., Kislitsina, K.S., Khazipova, A.N., and Kutepov, B.I., Russ. J. Org.Chem., 2013, vol. 49, no. 9, pp. 1273–1278.

    Article  CAS  Google Scholar 

  35. Grigor’eva, N.G., Bubennov, S.V., Khazipova, A.N., and Khalilov, L.M., Russ. Chem. Bull., 2013, no. 2, pp. 444–449.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Oil Chemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, Bashkortostan, 450075, Russia

    B. I. Kutepov, O. S. Travkina, I. N. Pavlova, A. N. Khazinova, N. G. Grigor’eva & M. L. Pavlov

  2. NTTs Salavatnefteorgsintez OOO, ul. Molodogvardeitsev 30, Salavat, Bashkortostan, 453256, Russia

    B. I. Kutepov, O. S. Travkina, I. N. Pavlova, A. N. Khazinova, N. G. Grigor’eva & M. L. Pavlov

Authors
  1. B. I. Kutepov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. S. Travkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. N. Pavlova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. N. Khazinova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. G. Grigor’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. M. L. Pavlov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. I. Kutepov.

Additional information

Original Russian Text © B.I. Kutepov, O.S. Travkina, I.N. Pavlova, A.N. Khazinova, N.G. Grigor’eva, M.L. Pavlov, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 1, pp. 70–77.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kutepov, B.I., Travkina, O.S., Pavlova, I.N. et al. New adsorbents and acid-base catalysts based on binder-free granulated zeolites of LTA and FAU types. Russ J Appl Chem 88, 65–71 (2015). https://doi.org/10.1134/S1070427215010103

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427215010103

Keywords

Search

Navigation