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Transformation pathways of o-xylene and its 4-substituted derivatives in the course of vapor-phase oxidative ammonolysis

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Data on formation pathways of two major products of oxidative ammonolysis of o-xylene and its 4-bromo and 4-phenyl derivatives, dinitrile and imide, whose formation involves competition of ammonia with oxygen and water on the surface of modified V-Sb-Bi/γ-Al2O3 oxide catalysts, are analyzed and summarized. In contrast to the competitive adsorption of ammonia and oxygen, the competitive adsorption of ammonia and water influences the transformation pathways of each substrate at both low and high ammonia concentrations.

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Authors and Affiliations

  1. Nagiyev Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, H. Javid ave. 113, Baku, AZ1143, Azerbaijan

    G. A. Bagirzade & D. B. Tagiyev

  2. Baku Higher Oil School, Khojaly ave. 30, Baku, AZ1025, Azerbaijan

    S. S. Fatullayeva

Authors
  1. G. A. Bagirzade
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  2. D. B. Tagiyev
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  3. S. S. Fatullayeva
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Correspondence to G. A. Bagirzade.

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Original Russian Text © G.A. Bagirzade, D.B. Tagiyeva, S.S. Fatullayeva, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 11, pp. 1636–1641.

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Bagirzade, G.A., Tagiyev, D.B. & Fatullayeva, S.S. Transformation pathways of o-xylene and its 4-substituted derivatives in the course of vapor-phase oxidative ammonolysis. Russ J Appl Chem 87, 1674–1679 (2014). https://doi.org/10.1134/S1070427214110172

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  • DOI: https://doi.org/10.1134/S1070427214110172

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