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Chemical modification of a random copolymer of styrene, isoprene, and butadiene, prepared by anionic polymerization in solution

  • Macromolecular Compounds and Polymeric Materials
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Abstract

A promising ternary copolymer of styrene, isoprene, and butadiene, synthesized by anionic polymerization in solution, was subjected to chemical postpolymerization modification using the following branching and endcapping agents: tin and silicon tetrachlorides, N-methylpyrrolidone, and Michler’s ketone. The combined method of chemical modification of the copolymer performed in the two-stream mode (branching and endcapping), with the subsequent mixing of the streams, is the most efficient.

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Correspondence to A. V. Budeeva.

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Original Russian Text © A.V. Budeeva, P.S. Lemport, S.V. Turenko, S.I. Vol’fson, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 10, pp. 1487–1499.

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Budeeva, A.V., Lemport, P.S., Turenko, S.V. et al. Chemical modification of a random copolymer of styrene, isoprene, and butadiene, prepared by anionic polymerization in solution. Russ J Appl Chem 87, 1536–1546 (2014). https://doi.org/10.1134/S107042721410022X

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  • DOI: https://doi.org/10.1134/S107042721410022X

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