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Synthesis and characterization of aliphatic-aromatic hyperbranched polyesters with high organosolubility

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Abstract

Carboxyl-terminated, water soluble, hyperbranched polyesters (HBPET) with aliphatic-aromatic structure were synthesized at three different monomer mole ratios (A3/B3 = 1: 1, 2: 1, 1: 2, respectively) by melt polycondensation of aconitic acid and phloroglucinol via A3+ B3 approach. Fourier transform infrared (FTIR) spectroscopy indicated as that was expected HBPET, which showed excellent solubility in a variety of polar solvents such as N,N-dimethyl formamide (DMF), N-methyl-2-pyrrolidone (NMP), dimethyl sulfoxide (DMSO), and tetrahydrofuran (THF). The weight-average molecular weight of HBPET ranged from 7792 to 9214 g mol−1 and their intrinsic viscosity were varied from 0.17 to 0.34 dL g−1. The degree of branching of the HBPET was estimated to be 0.44–0.49 by 1H and 13C NMR measurement. The thermogravimetric analysis (TGA) measurement revealed that HBPET was of 10% weight-loss at 340°C in N2.

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Authors and Affiliations

  1. College of Materials Science and Engineering, State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai, 201620, China

    Haroon A. M. Saeed, Yassir A. Eltahir, Yumin Xia & Yimin Wang

  2. Faculty of Textiles, University of Gezira, Wad-medani, P.O. Box 20, Sudan

    Haroon A. M. Saeed & Yassir A. Eltahir

Authors
  1. Haroon A. M. Saeed
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  2. Yassir A. Eltahir
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  3. Yumin Xia
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  4. Yimin Wang
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Correspondence to Yimin Wang.

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Saeed, H.A.M., Eltahir, Y.A., Xia, Y. et al. Synthesis and characterization of aliphatic-aromatic hyperbranched polyesters with high organosolubility. Russ J Appl Chem 87, 1481–1488 (2014). https://doi.org/10.1134/S1070427214100140

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  • DOI: https://doi.org/10.1134/S1070427214100140

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