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Synthesis of bicyclo[2.2.1]heptyl oxyalkanes and acrylates based on them

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Addition reactions of ethane-1,2-diol, propane-1,3-diol, and butane-1,4-diol to bicyclo[2,2,1]hept-2-ene in the presence of a catalyst BF3 OEt2 were studied for deriving reactive monomer, therewith bicyclo[2.2.1] hept-2-oxyalcanols with a yield of 91.2–96.0% were synthesized. In the second stage esterification of the obtained bicyclo[2.2.1]hept-2-oxyalkanols was conducted with acrylic acid in the presence of a catalyst of KU-2-8 H grade and acrylates was also derived with a yield of 87.5–93.0%, which are reactive monomers for synthesis of polymeric glassy products.

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Authors and Affiliations

  1. Mammedaliev Institute of Petrochemical Processes, National Academy of Sciences, pr. Khodzhaly 30, Baku, AZ1025, Azerbaijan

    M. K. Mamedov, G. N. Mekhtieva & Kh. G. Gurbanova

Authors
  1. M. K. Mamedov
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  2. G. N. Mekhtieva
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  3. Kh. G. Gurbanova
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Correspondence to M. K. Mamedov.

Additional information

Original Russian Text © M.K. Mamedov, G.N. Mekhtieva, Kh.G. Gurbanova, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 10, pp. 1445–1448.

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Mamedov, M.K., Mekhtieva, G.N. & Gurbanova, K.G. Synthesis of bicyclo[2.2.1]heptyl oxyalkanes and acrylates based on them. Russ J Appl Chem 87, 1446–1449 (2014). https://doi.org/10.1134/S1070427214100097

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  • DOI: https://doi.org/10.1134/S1070427214100097

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