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The investigation of the structure control possibility of nanocrystalline yttrium orthoferrite in its synthesis from amorphous powders

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Mechanism by which nanocrystalline yttrium orthoferrite is formed in thermal treatment of amorphous nanopowders produced by the glycine-nitrate combustion method was studied. It was shown that orthorhombic YFeO3 is formed from the amorphous phase via intermediate formation of a metastable nanocrystalline hexagonal phase of yttrium orthoferrite. The main parameter controlling the process in which the orthorhombic form of YFeO3 is determined. It was demonstrated that YFeO3 crystallizes from an amorphous powder in the hexagonal modification up to nanocrystal sizes of approximately 33 nm and transforms to the orthorhombic phase at larger sizes.

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References

  1. Jacob, K.T. and Rajitha, G., Solid State Ionics, 2012, vol. 224, pp. 32–40.

    Article  CAS  Google Scholar 

  2. Shang, M., Zhang, C., Zhang, T., et al., Appl. Phys. Lett., 2013, vol. 102, no. 6, p. 062903.

    Article  CAS  Google Scholar 

  3. Markova-Velichkova, M., Lazarova, T., Tumbalev, V., et al., Chem. Eng. J., 2013, vol. 231, pp. 236–244.

    Article  CAS  Google Scholar 

  4. Wang, W., Li, S., Wen, Y., et al., Acta Phys.-Chim. Sinica, 2008, vol. 24, no. 10, pp. 1761–1766.

    Article  CAS  Google Scholar 

  5. Dinh, V.T., Mittova, V.O., Almjasheva, O.V., Mittova, I.Ya., Inorg. Mater., 2011, vol. 47, no. 10, pp. 1141–1146.

    Article  CAS  Google Scholar 

  6. Nguyen, A.T., Mittova, I.Ya., Solodukhin, D.O., et al., Russ. J. Inorg. Chem., 2014, vol. 59, no. 2, pp. 40–45.

    Article  CAS  Google Scholar 

  7. Nguyen, A.T., Mittova, I.Ya., Almjasheva, O.V., et al., Glass Phys. Chem., 2008, vol. 34, no. 6, pp. 756–761.

    Article  CAS  Google Scholar 

  8. Cao, X., Kim, Ch.-S., and Yoo, H.-I., J. Am. Ceram. Soc., 2001, vol. 84, no. 6, pp. 1265–1272.

    Article  CAS  Google Scholar 

  9. Wang, J., Dong, X., Qu, Z., et al., Modern Appl. Sci., 2009, vol. 3, no. 9, pp. 65–71.

    Google Scholar 

  10. Khetre, S.M., Jadhav, H.V., Jagadale, P.N., et al., J. Appl. Sci. Res., 2011, vol. 2, no. 4, pp. 503–511.

    CAS  Google Scholar 

  11. Wang, J., Liu, Q., Xue, D., and Li, F., J. Mater. Sci. Lett., 2002, vol. 21, no. 13, pp. 1059–1062.

    Article  CAS  Google Scholar 

  12. Popa, M. and Moreno, J.M.C., J. Alloys Compounds, 2011, vol. 509, pp. 4108–4116.

    Article  CAS  Google Scholar 

  13. Nguyen, A.T., Knurova, M.V., Nguyen, T.M., et al., Nanosyst.: Phys., Chem., Math., 2014, vol. 5, no. 5, pp. 692–702.

    Google Scholar 

  14. Zhou Z., Guo L., Yang H. et al. J. Alloys a. Compounds. 2014, vol. 583, pp. 21–31.

    Article  CAS  Google Scholar 

  15. Tugova, E.A. and Zvereva, I.A., Nanosyst.: Phys., Chem., Math., 2013, vol. 4, no. 6, pp. 851–856.

    Google Scholar 

  16. Stathopoulos, V.N., Belessi, V.C., and Ladavos, A.K., React. Kinet. Catal. Lett., 2001, vol. 72, no. 1, pp. 49–55.

    Article  CAS  Google Scholar 

  17. Morozov, M.I., Lomanova, N.A., and Gusarov, V.V., Russ. J. Gen. Chem., 2003, vol. 73, no. 11, pp. 1676–1680.

    Article  CAS  Google Scholar 

  18. Golubeva, O.Yu., Gusarov, V.V., Semenov, V.G., and Volodin, V.S., Glass Phys. Chem., 2009, vol. 35, no. 3, pp. 313–319.

    Article  CAS  Google Scholar 

  19. Lomanova, N.A. and Gusarov, V.V., Nanosyst.: Phys., Chem., Math., 2013, vol. 4, no. 5, pp. 696–705.

    CAS  Google Scholar 

  20. Liu, J., Zhang, H., Gu, Z., and Xie, J., Mater. Sci. Forum, 2007, vols. 561–565, pp. 1085–1088.

    Article  Google Scholar 

  21. Maiti, R., Basu, S., and Chakravorty, D., J. Magn. Magn. Mater., 2009, vol. 321, no. 19, pp. 3274–3277.

    Article  CAS  Google Scholar 

  22. Nguyen, A.T., Mittova, I.Ya., and Almjasheva, O.V., Russ. J. Appl. Chem., 2009, vol. 82, no. 11, pp. 1915–1918.

    Article  CAS  Google Scholar 

  23. Nguyen, A.T., Almjasheva, O.V., Mittova, I.Ya., et al., Inorg. Mater., 2009, vol. 45, no. 11, pp. 1304–1308.

    Article  CAS  Google Scholar 

  24. Tang, P., Sun, H., Chen, H., and Cao, F., Curr. Nanosci., 2012, vol. 8, pp. 64–67.

    Article  CAS  Google Scholar 

  25. Zhang, Y., Yang, J., Xu, J., et al., Mater. Lett., 2012, vol. 81, pp. 1–4.

    Article  CAS  Google Scholar 

  26. Zhang, W., Fang, C., Yin, W., and Zeng, Y., Mater. Chem. Phys., 2013, vol. 137, pp. 877–883.

    Article  CAS  Google Scholar 

  27. Popkov, V.I. and Almjasheva, O.V., Nanosyst.: Phys., Chem., Math., 2014, vol. 5, no. 5, pp. 703–708.

    Google Scholar 

  28. Tang, P., Chen, H., Cao, F., and Pan, G., Catal. Sci. Technol., 2011, vol. 1, pp. 1145–1148.

    Article  CAS  Google Scholar 

  29. Gusarov, V.V., Russ. J. Gen. Chem., 1997, vol. 67, no. 12, pp. 1846–1851.

    CAS  Google Scholar 

  30. Kondakindi, R.R., Karan, R., and Peppley, B.A., Ceram. Int., 2012, vol. 38, pp. 449–456.

    Article  CAS  Google Scholar 

  31. Wu, L., Yu, J.C., Zhang, L., et al., J. Solid State Chem., 2004, vol. 177, no. 10, pp. 3666–3674.

    Article  CAS  Google Scholar 

  32. Zhuravlev, V.D., Vasiliev, V.G., Vladimirova, E.V., et al., Glass Phys. Chem., 2010, vol. 36, no. 4, pp. 506–512.

    Article  CAS  Google Scholar 

  33. Komlev, A.A. and Vilezhaninov, E.F., Russ. J. Appl. Chem., 2013, vol. 86, no. 9, pp. 1344–1350.

    Article  CAS  Google Scholar 

  34. Komlev, A.A. and Gusarov, V.V., Inorg. Mater., 2014, vol. 50, no. 12, pp. 1247–1251.

    Article  CAS  Google Scholar 

  35. Popkov, V.I. and Almjasheva, O.V., Russ. J. Appl. Chem., 2014, vol. 87, no. 2, pp. 167–171.

    Article  CAS  Google Scholar 

  36. Patterson, A., Phys. Rev., 1939, vol. 56, pp. 978–982.

    Article  CAS  Google Scholar 

  37. Gusarov, V.V. and Almjasheva, O.V., Nanomaterials: Properties and Perspective Applications, Yaroslavtsev, A.B., Exec. Ed., Moscow: Scientific world, 2014.

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Correspondence to V. I. Popkov.

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Original Russian Text © V.I. Popkov, O.V. Almjasheva, V.V. Gusarov, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 10, pp. 1416–1420.

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Popkov, V.I., Almjasheva, O.V. & Gusarov, V.V. The investigation of the structure control possibility of nanocrystalline yttrium orthoferrite in its synthesis from amorphous powders. Russ J Appl Chem 87, 1417–1421 (2014). https://doi.org/10.1134/S1070427214100048

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  • DOI: https://doi.org/10.1134/S1070427214100048

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