Abstract
Modern research techniques with radioactive isotopes were used to study the transport characteristics, (conductivity and diffusion) in chalcogenide membrane materials of the Ag2S-As2S3-TlI system. It was demonstrated that, on raising the silver sulfide concentration in a glass, the total electrical conductivity grows by two orders of magnitude, which is due to the pronounced change of the band structure and to the increase in the electronic component of the conductivity. New chemical sensors for determination Tl ions in solutions were developed on the basis of these solid-state studies.
Similar content being viewed by others
References
Aguilar-Martnnez, R., Gumez-Gumez, M.M., Greenwood, R., et al., Talanta, 2009, vol. 77, no. 4, pp. 1483–1489.
Ion, A.C., Ion, I., Stefan, D.N., and Barbu, L., Mater. Sci. Eng. C, 2009, vol. 29, no. 1, pp. 1–4.
Schöning, M.J. and Kloock, J.P., Electroanalysis, 2007, vol. 19, nos. 19–20, pp. 2029–2038.
Singh, P.R. and Contractor, A.Q., Int. J. Environ. Anal. Chem., 2005, vol. 85, nos. 12–13, pp. 831–835.
Huang, M.-R., Ding, Y.-B., and Li, X.-G., Analyst, 2013, vol. 138, no. 13, pp. 3820–3829.
Kloock, J.P., Moreno, L., Bratov, A., et al., Sens. Actuators B, 2006, vol. 118, pp. 149–155.
Martins, G.F., Pereira, A.A., Straczalano, B.A., et al., Sens. Actuators B, 2008, vol. 129, no. 2, pp. 525–530.
Sarkar, S. and Shunmugam, R., ACS Appl. Mater. Interfaces, 2013, vol. 5, no. 15, pp. 7379–7383.
Li, M., Lu, H.-Y., Liu, R.-L., et al., J. Org. Chem., 2012, vol. 77, no. 7, pp. 3670–3673.
Singh, A.K. and Mehtab, S., Talanta, 2008, vol. 74, no. 4, pp. 806–814.
Ermolenko, Yu.E., Kalyagin, D.S., Subbotina, S.N., et al., Russ. J. Appl. Chem., 2013, vol. 86, no. 2, pp. 192–199.
Yamamoto, M. and Tsuchiya, N., Radiat. Prot. Dosim., 2006, vol. 119, nos. 1–4, pp. 119–123.
Hassan, S.S.M., Abou Ghalia, M.H., Amr, A.-G.E., and Mohamed, A.H.K., Anal. Chim. Acta, 2003, vol. 482, no. 1, pp. 9–18.
Lucas, P., King, E.A., Gulbiten, O., et al., Phys. Rev. B: Condens. Matter Mater. Phys., 2009, vol. 80, no. 21, Art. No. 214114.
Grygolowicz-Pawlak, E., Crespo, G.A., Ghahraman, Afshar M., et al., Anal. Chem., 2013, vol. 85, no. 13, pp. 6208–6212.
Gupta, V.K., Chimia, 2005, vol. 59, no. 5, pp. 209–217.
Matsunaga, T., Akola, J., Kohara, S., et al., Nat. Mater., 2011, vol. 10, no. 2, pp. 129–134.
Fan, X., White, I.M., Shopova, S.I., et al., Anal. Chim. Acta, 2008, vol. 620, nos. 1–2, pp. 8–26.
Gupta, V.K. and Agarwal, S., Talanta, 2005, vol. 65, no. 3, pp. 730–734.
Amemiya, S., Handbook of Electrochem., 2007, pp. 261-294.
Vlasov, Yu.G., Khimicheskie sensory (Chemical Sensors), vol. 14, Nauka, 2011.
Jorge, E.O., Neto, M.M.M., and Rocha, M.M., Talanta, 2007, vol. 72, pp. 1392–1399.
Singh, A.K. and Saxena, P., Talanta, 2005, vol. 66, pp. 993–998.
Vlasov, Yu.G. and Bychkov, E.A., Ion-Sel. Electrode Rev., 1987, vol. 9, pp. 3–92.
Massobrio, C., Celino, M., Salmon, P.S., et al., Phys. Rev. B: Condens. Matter Mater. Phys., 2009, vol. 79, no. 17, Art. no. 174201.
Conde Garrido, J.M., Uresa, M.A., and Arcondo, B., J. Alloys Compd., 2010, vol. 495, no. 2, pp. 356–359.
Boukamp, B.A., Equivalent Circuit: User’s Manual, University of Twente, 1988.
Ivanov-Shits, A.K. and Murin, I.V., Ionika tverdogo tela (Solid State Ionics), vol. 1, St. Petersburg, Gos. Univ., 2000.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © D.S. Kalyagin, Yu.E. Ermolenko, I.E. Alekseev, E.A. Bychkov, S.A. Krotov, N.A. Mel’nikova, I.V. Murin, Yu.G. Vlasov, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 8, pp. 1059–1063.
Rights and permissions
About this article
Cite this article
Kalyagin, D.S., Ermolenko, Y.E., Alekseev, I.E. et al. Ag2S-As2S3-TlI chalcogenide glasses as perspective material for solid-state chemical sensors. Russ J Appl Chem 87, 1044–1048 (2014). https://doi.org/10.1134/S1070427214080060
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427214080060