Abstract
The catalytic properties of zeolites HY, HBeta, and HZSM-12 and of mesoporous amorphous aluminosilicate in liquid-phase esterification of aliphatic (monobasic C1–C18, dibasic C6, C10) and aromatic (benzoic, trimellitic, phthalic) carboxylic acids with butanol were studied. Zeolite HBeta appeared to be the most active catalyst. Procedures were developed for preparing esters in the presence of zeolitic catalyst HBeta, ensuring 100% selectivity of ester formation at 90–98% conversion of the acid.
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Original Russian Text © N.G. Grigor’eva, A.M. Suleimanova, M.R. Agliullin, B.I. Kutepov, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 6, pp. 767–774.
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Grigor’eva, N.G., Suleimanova, A.M., Agliullin, M.R. et al. Synthesis of carboxylic acid esters in the presence of micro- and mesoporous aluminosilicates. Russ J Appl Chem 87, 773–779 (2014). https://doi.org/10.1134/S1070427214060184
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DOI: https://doi.org/10.1134/S1070427214060184