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Low temperature isomerization of n-hexane on catalyst systems Al2O3/ZrO2/SO4/Pt

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Abstract

As a result of investigating low temperature isomerization of n-hexane at 130, 140, 150, 160°C in a flow reactor with a fixed bed of catalyst of the Al2O3/ZrO2/SO4/Pt type a ratio of components in the catalyst system was selected and process conditions were defined, which allow to obtain highly branched high-octane isomers with a yield of up to 40% relative to a transformed raw material. A kinetic model of the process was proposed and kinetic parameters were calculated.

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Authors and Affiliations

  1. St. Petersburg State Technological Institute (Technical University), Moskovskii pr. 26, St. Petersburg, 190013, Russia

    E. V. Chuparev, P. A. Zernov, O. I. Parputs & N. V. Lisitsyn

  2. JSC “RRT Ltd.”, ul. Serpukhovskaya 10, St. Petersburg, 190013, Russia

    E. V. Chuparev, P. A. Zernov & O. I. Parputs

Authors
  1. E. V. Chuparev
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  2. P. A. Zernov
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  3. O. I. Parputs
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  4. N. V. Lisitsyn
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Corresponding author

Correspondence to E. V. Chuparev.

Additional information

Original Russian Text © E.V. Chuparev, P.A. Zernov, O.I. Parputs, N.V. Lisitsyn, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 6, pp. 760–766.

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Chuparev, E.V., Zernov, P.A., Parputs, O.I. et al. Low temperature isomerization of n-hexane on catalyst systems Al2O3/ZrO2/SO4/Pt. Russ J Appl Chem 87, 767–772 (2014). https://doi.org/10.1134/S1070427214060172

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  • DOI: https://doi.org/10.1134/S1070427214060172

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