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A study of the preparation conditions of aluminum oxide on its catalytic activity and stability in vapor-phase dehydration of glycerol to acrolein

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Abstract

Effect of the preparation conditions of aluminum oxide on its catalytic activity and stability in the course of vapor-phase dehydration of glycerol to give acrolein was studied. The conditions were determined in which γ-Al2O3 is prepared so that the maximum selectivity of acrolein formation (∼60%) and glycerol conversion (∼80%) is in 10 h. The results of the study suggest that systems based on γ-Al2O3 are the most promising catalysts for the process under consideration.

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Correspondence to A. S. Belousov.

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Original Russian Text © S.M. Danov, A.L. Esipovish, A.S. Belousov, A.E. Rogozhin, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 6, pp. 746–752.

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Danov, S.M., Esipovish, A.L., Belousov, A.S. et al. A study of the preparation conditions of aluminum oxide on its catalytic activity and stability in vapor-phase dehydration of glycerol to acrolein. Russ J Appl Chem 87, 754–760 (2014). https://doi.org/10.1134/S1070427214060159

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  • DOI: https://doi.org/10.1134/S1070427214060159

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