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Synthesis of sorption materials based on dithiooxamidate aminopropyl polysiloxane

  • Sorption and Ion Exchange Processes
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Abstract

Reaction of reamidation of rubeanic acid with aminopropyl polysiloxane was systematically studied. It was found that the given type of transformations make it possible to obtain a derivative of aminopropyl polysiloxane with surface dithiooxamide groups in a concentration of up to 0.78 mmol g−1 at a total degree of substitution of up to 0.25. The composition and structure of the derivatives obtained were characterized by elemental analysis, IR spectroscopy, thermogravimetry, and method of low-temperature adsorption of nitrogen. The sorption of Ni(II), Pd(II), and Pt(II) in a 0.2 M solution of hydrochloric acid was evaluated for the products obtained.

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Authors and Affiliations

  1. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi 22, Yekaterinburg, 620137, Russia

    I. S. Puzyrev, A. V. Mekhaev & A. V. Pestov

  2. Ural Federal University named after the first President of Russia B.N. Yeltsin, ul. Mira 19, Yekaterinburg, 620002, Russia

    A. S. Kholmogorova & L. K. Neudachina

Authors
  1. I. S. Puzyrev
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  2. A. S. Kholmogorova
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  3. L. K. Neudachina
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  4. A. V. Mekhaev
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  5. A. V. Pestov
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Correspondence to I. S. Puzyrev.

Additional information

Original Russian Text © I.S. Puzyrev, A.S. Kholmogorova, L.K. Neudachina, A.V. Mekhaev, A.V. Pestov, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 6, pp. 721–726.

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Puzyrev, I.S., Kholmogorova, A.S., Neudachina, L.K. et al. Synthesis of sorption materials based on dithiooxamidate aminopropyl polysiloxane. Russ J Appl Chem 87, 715–719 (2014). https://doi.org/10.1134/S1070427214060081

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  • DOI: https://doi.org/10.1134/S1070427214060081

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