Skip to main content
SpringerLink
Log in

One-pot synthesis of bis-1,5,3-dithiazepanes and their sorption properties toward silver(I) and palladium(II)

  • Sorption and Ion Exchange Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

The possibility of one-pot synthesis of bis-1,5,3-dithiazepanes by multicomponent condensation of amines (NH4Cl, hydrazine, and 1,2-ethylenediamine) with formaldehyde and 1,2-ethanedithiol was described. Their sorption properties relative to Ag(I) and Pd(II) were studied by a static method. It was shown that at room temperature bis-1,5,3-dithiazepanes recovered with high efficiency silver(I) and palladium(II) from nitrate solutions and hydrochloric acid solutions, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Buslaeva, T.M., Gromov, S.P., and Sidorenko, N.I., Ros. Khim. Zh., 2006, vol. 50, no. 4, pp. 26–35.

    CAS  Google Scholar 

  2. Murinov, Yu.I., Maistrenko, V.N., and Afzaletdinova, N.G., Ekstraktsiya metallov S,N-organicheskimi soedineniyami (Extraction of Metals with S,N-Organic Compounds), Moscow: Nauka, 1993.

    Google Scholar 

  3. Akhmetova, V.R., Nadyrgulova, G.R., Niatshina, Z.T., and Dzhemilev, U.M., Chem. Heterocyclic. Comp., 2009, no. 10, pp. 1155–1176.

    Google Scholar 

  4. Akhmetova, V.R., Khabibullina, G.R., Rakhimova, E.B., et al., Mol. Div., 2010, no. 14, pp. 463–471.

    Google Scholar 

  5. Khafizova, S.R., Akhmetova, V.R., Korzhova, L.F. et al., Russ. Chem. Bull. Int. Ed., 2012, no. 11, pp. 432–436.

    Google Scholar 

  6. Anpilogova, G.R., Akhmadiev, N.S., Khabibullina, G.R., and Akhmetova, V.R., Russ. J. Appl. Chem., 2011, no. 5, pp. 786–791.

    Google Scholar 

  7. Ito, K. and Sekiya, M., Chem. Pharm. Bull., 1979, vol. 27, no. 7, pp. 1691–1694.

    Article  CAS  Google Scholar 

  8. Murzakova, N.N., Prokof’ev, K.I., Tyumkina, T.V., Ibragimov, A.G., Russ. J. Org. Chem., 2012, no. 4, pp. 588–593.

    Google Scholar 

  9. Khabibullina, G.R., Akhmetova, V.R., Bushmarinov, I.S., Ibragimov, A.G., Russ. J. Org. Chem., 2013, no. 10, pp. 1542–1545.

    Google Scholar 

  10. Akhmetova, V.R., Murzakova, N.N., Tyumkina, T.V., et al., Russ. Chem. Bull. Int. Ed., 2012, no. 11, pp. 2140–2148.

    Google Scholar 

  11. Rakhimova, E.B., Efremova, E.A., Bushmarinov, I.S., et al., Tetrahedron Lett., 2012, vol. 53, pp. 4225–4227.

    Article  CAS  Google Scholar 

  12. Schöniger, W., Mikrochim. Acta, 1956, vols. 5–6, p. 869.

    Article  Google Scholar 

  13. Rakhimova, E.B., Ismagilov, R.A., Zainullin, R.A., et al., Chem. Heterocyclic Comp., 2013, no. 8, pp. 1237–1242.

    Google Scholar 

  14. Rakhimova, E.B., Ismagilov, R.A., Zainullin, R.A., et al., Russ. J. Appl. Chem., 2013, no. 10, pp. 1504–1508

    Google Scholar 

  15. Ginzburg, E.G., Ezerskaya, N.Z., Prokof’eva, S.M., et al., Analiticheskaya khimiya platinovykh metallov (Analytical Chemistry of Platinum Metals), Moscow: Khimiya, 1972, 613 p.

    Google Scholar 

  16. Vasil’ev, V.P. Analiticheskaya khimiya (Analytical Chemistry), ch. 1, Moscow: Vysshaya Shkola, 1989, 320 p.

    Google Scholar 

  17. Anpilogova, G.R., Kondrat’eva, E.V., Afzaletdinova, N.G., et al., Russ. J. Inorg. Chem., 1996, vol. 41, no. 3, pp. 429–434.

    Google Scholar 

  18. Matrosov, E.I., Starikova, Z.A., Yanovskii, A.I., et al., Russ. Chem. Bull. Int. Ed., 1988, no. 9, pp. 1702–1709.

    Google Scholar 

  19. Saldadze, K.M., and Kopylova-Valova, V.D., Kompleksoobrazuyushchie ionity (kompleksity) [Complexing Ion Exchange Agents (Complexities)], Moscow: Khimiya, 1980, 336 p.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Russia

    V. R. Akhmetova, G. R. Khabibullina, N. S. Akhmadiev & A. G. Ibragimov

  2. Institute of Organic Chemistry, Ufa Scientific Centre, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Russia

    G. R. Anpilogova

Authors
  1. V. R. Akhmetova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. R. Anpilogova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. R. Khabibullina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. S. Akhmadiev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. G. Ibragimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. R. Akhmetova.

Additional information

Original Russian Text © V.R. Akhmetova, G.R. Anpilogova, G.R. Khabibullina, N.S. Akhmadiev, A.G. Ibragimov, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 5, pp. 595–600.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Akhmetova, V.R., Anpilogova, G.R., Khabibullina, G.R. et al. One-pot synthesis of bis-1,5,3-dithiazepanes and their sorption properties toward silver(I) and palladium(II). Russ J Appl Chem 87, 585–590 (2014). https://doi.org/10.1134/S1070427214050085

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427214050085

Keywords

Search

Navigation