Abstract
Organomineral composite sorbents KU-2×8-ZnS and KU-2×8-PbS were synthesized on the basis of the matrix of a strongly acidic KU-2×8 cation exchanger. Scanning electron microscopy and elemental analysis were used to study their microstructure and chemical composition. With the use of potentiometric titration, their bifunctional nature was revealed and the dissociation constants and the total exchange capacities of the ionogenic groups were determined. The sorption of copper(II), zinc, and cadmium by KU-2×8-ZnS and KU-2×8-PbS sorbents from 0.005 M solutions of their salts was examined. The total dynamic sorption capacity of the composite sorbents for the above metals, found in the study, exceeds similar values for the individual KU-2×8 cation exchanger by a factor of 1.6–2.0 and that in 0.001–0.050 M solutions of potassium and calcium chlorides, by a factor of 1.3–4.5. An explanation is suggested for the sorption process of heavy nonferrous metals on composite sorbents with an active sulfide component by the mechanism of coordination copolymerization.
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References
Lebedev, K.B., Kazantsev, E.I., Pakholkov, V.S., et al., Ionity v tsvetnoi metallurgii (Ion Exchangers in Nonferrous Metallurgy), Moscow: Metallurgiya, 1975.
Skorokhodov, V.I., Anikin, Yu.V., Radionov, B.K., et al., Tsv. Met., 2000, nos. 11–12, pp. 71–74.
Doula, M.K. and Dimirkou, A., J. Hazard. Mater., 2008, vol. 151, pp. 738–745.
Trochimczuk, A.W., Bozena, N. Kolarz, and Dorota Jermakowicz-Bartkowiak, J. Eur. Polymer., 2001, pp. 559–564.
Bekrenev, A.V. and Pyartman, A.K., Zh. Neorg. Khim., 1995, vol. 40, no. 6, pp. 938–942.
Bekrenev, A.V. and Pyartman, A.K., Zh. Neorg. Khim., 1995, vol. 40, no. 6, pp. 943–947.
Markov, V.F., Paznikova, S.N., Maskaeva, L.N., et al., Tsv. Met., 2008, no. 9, pp. 39–42.
Markov, V.F., Maskaeva, L.N., and Ikanina, E.V., Sorbts. Khromatogr. Protsessy, 2010, vol. 10, no. 6, pp. 830–839.
Vol’khin, V.V. and L’vovich, V.I., Prigotovlenie trudnorastvorimykh gidratirovannykh sul’fidov v granulirovannoi forme i ikh sorbtsionnye svoistva. Sintez i svoistva ionoobmennykh materialov (Preparation of Difficultly Soluble Hydrasted Sulfides in the Granulated Form and Their Sorption Properties. Synthesis and Properties of Ion-Exchange Materials), Moscow: Nauka, 1977, pp. 73–77.
Bobylev, A.E., Ikanina, E.V., Markov, V.F., and Maskaeva, L.N., Kondens. Sredy Mezhfazn. Granitsy, vol. 15, no. 3, pp. 238–246.
Polyanskii, N.G., Gorbunov, G.V., and Polyanskaya, N.L., Metody issledovaniya ionitov (Methods for Study of Ion Exchangers), Moscow: Khimiya, 1976.
Helfferich, F., Ion exchange, New York: Dover Publications Inc., 1995.
Venitsianov, E.V. and Rubinshtein, R.N., Dinamika sorbtsii iz zhidkikh sred (Dynamics of Sorption from Liquid Media), Moscow: Nauka, 1983.
Kokotov, Yu.A. and Pasechnik, V.A., Ravnovesie i kinetika ionnogo obmena (Equilibrium and Kinetics of Ion Exchange), Leningrad: Khimiya, 1970.
Chatlot, G., Qualitative Inorganic Analysis, Thomas Press, 2007.
Markov, V.F., Maskaeva, L.N., and Ivanov, P.N., Gidrokhimicheskoe osazhdenie plenok sul’fidov metallov: Modelirovanie i eksperiment (Hydrochemical Deposition of Metal Sulfide Films. Simulation and Experiment), Yekaterinburg: Ural. Otd. Ross. Akad. Nauk, 2006.
Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook of Analytical Chemistry), Moscow: Khimiya, 1971.
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Original Russian Text © A.E. Bobylev, V.F. Markov, L.N. Maskaeva, A.Yu. Chufarov, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 5, pp. 581–588.
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Bobylev, A.E., Markov, V.F., Maskaeva, L.N. et al. Composition, structure, and functional properties of organomineral composite sorbents KU-2×8-ZnS and KU-2×8-PbS. Russ J Appl Chem 87, 572–578 (2014). https://doi.org/10.1134/S1070427214050061
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DOI: https://doi.org/10.1134/S1070427214050061