Abstract
Results of a study of the influence exerted by the cation composition on the bulk and surface properties of modified lignosulfonates are reported. It was found that the dissolution of lignosulfonic acids is accompanied by dissociation and conformational transitions of macromolecules, which leads to concentration of molecules of lignosulfonic acids in the solution bulk and, as a consequence, to a substantial increase in the surface tension.
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Lugovitskaya, T.N., Bolatbaev, K.N., and Naboichenko, S.S., Kompleks. Ispol’z. Mineral’nogo Syr’ya, 2013, no. 4, pp. 16–20.
Lugovitskaya, T.N., Bolatbaev, K.N., and Naboichenko, S.S., Russ. J. Gen. Chem., 2014, vol. 84, no. 2, pp. 309–312.
Lugovitskaya, T.N. and Bolatbaev, K.N., Russ. J. Appl. Chem., 2013, vol. 86, no. 8, pp. 1280–1286.
Baranova, V.I., Bibik, E.E., Kozhevnikova, N.M., et al., Praktikum po kolloidnoi khimii (Laboratory Course of Colloid Chemistry), Moscow: Vysshaya Shkola, 1983.
Brovko, O.S., Palamarchuk, I.A., Makarevich, N.A., and Boitsova, T.A., Khim. Rastit. Syr’ja, 2009, no. 1, pp. 29–36.
Semchikov, Yu.D., Vysokomolekulyarnye soedineniya (Macromolecular Compounds), Moscow: Academia, 2003.
Shershavina, A.A., Fizicheskaya i kolloidnaya khimiya (Physical and Colloid Chemistry), Moscow: OOO Novoe Znanie, 2005.
Ligniny. Struktura, svoistva i reaktsii (Lignins: Structure, Properties, and Reactions), Sarkanen, K.V. and Lyudvig, K.Kh., Eds., Moscow: Khimiya, 1975.
Praktikum po vysokomolekulyarnym soedineniyam (Laboratory Course of Macromolecular Compounds), Kabanov, V.A., Ed., Moscow: Khimiya, 1985.
Afanas’ev, N.I., Tel’tevskaya, S.E., Makarevich, N.A., and Parfenova, L.N., Struktura i fiziko-khimicheskie svoistva lignosul’fonatov (Structure and Physicochemical Properties of Lignosulfonates), Yekaterinburg: Ural. Otd. Ross. Akad. Nauk, 2005.
Makarevich, N.A., Afanas’ev, N.I., Palamarchuk, I.A., and Boitsova, T.A., Izv. Nats. Akad. Nauk Belarusi, 2013, no. 3, pp. 23–31.
Osnovy analiticheskoi khimii. Prakticheskoe rukovodstvo: Uchebnoe posobie dlya vysshikh uchebnykh zavedenii (Fundamentals of Analytical Chemistry, Laboratory Manual, Textbook for Higher School), Zolotov, Yu.A., Ed., Moscow: Vysshaya Shkola, 2001.
Bogolitsyn, K.G. and Reznikov, V.M., Khimiya sul’fitnykh metodov delignifikatsii drevesiny (Chemistry of Sulfite Methods for Delignification of Wood), Moscow: Ekologiya, 1994.
Tarnaroutski, G.M., Gribanova, N.V., Telisheva, G.M., and Sergeeva, V.N., Int. 7th Congr. Int. Chimie des Ciments, Paris, 1980, vol. 3, pp. 153–157.
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Original Russian Text © T.N. Lugovitskaya, K.N. Bolatbaev, K.A. Ostrovnoi, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 4, pp. 433–439.
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Lugovitskaya, T.N., Bolatbaev, K.N. & Ostrovnoi, K.A. Bulk and surface properties of lignosulfonic acids and their salts. Russ J Appl Chem 87, 428–433 (2014). https://doi.org/10.1134/S1070427214040053
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DOI: https://doi.org/10.1134/S1070427214040053