Skip to main content
SpringerLink
Log in

Synthesis of block copolymers from polyvinyl chloride prepared in the presence of nitroxyl radicals of the imidazoline series

  • Macromolecular Compounds and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Specific features of radical polymerization of vinyl chloride in the presence of nitroxyl radicals of the imidazoline series (2-methyl-2,3-diphenyl-1,4-diazaspiro[4,5]dec-3-ene-1-oxyl, 2,2,5,5-tetramethyl-4-phenyl-2,5-dihydroimidazole-1-oxyl, 2,2,5-trimethyl-4,5-diphenyl-2,5-dihydroimidazole-1-oxyl) were studied. The possibility of preparing vinyl chloride-styrene block copolymers in the presence of these nitroxyl radicals was demonstrated, suggesting the occurrence of the polymerization by the reversible inhibition mechanism. The molecular-mass characteristics and the glass transition points of the synthesized samples were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Wei-Fang Su, Principles of Polymer Design and Synthesis, New York: Springer, 2013.

    Book  Google Scholar 

  2. Nikolas, J., Guillaneuf, Y., Catherine, L., et al., Prog. Polym. Sci., 2013, vol. 38, no. 1, pp. 63–235.

    Article  Google Scholar 

  3. Endo, K., Prog. Polym. Sci., 2002, vol. 27, pp. 2021–2054.

    Article  CAS  Google Scholar 

  4. Wannemacher, T., Brawn, D., and Pfaeudner, R., Macromol. Symp., 2003, vol. 202, no. 1, pp. 11–23.

    Article  CAS  Google Scholar 

  5. Abbasian, A. and Entezami, A.A., Polym. Adv. Technol., 2007, vol. 18, pp. 306–312.

    Article  CAS  Google Scholar 

  6. Satoh, K., Kamigaito, M., and Sawamoto, M., Polym. Sci. A. Compreh. Ref., 2012, vol. 3, pp. 429–468.

    Article  Google Scholar 

  7. Kolyakina, E.V. and Grishin, D.F., Russ. Chem. Rev., 2009, vol. 78, no. 6, pp. 535–568.

    Article  CAS  Google Scholar 

  8. Grishin, D.F. and Grishin, I.D., Russ. J. Appl. Chem., 2011, vol. 84, no. 12, pp. 2021–2029.

    Article  CAS  Google Scholar 

  9. di Lena, F. and Matyjaszewski, K., Prog. Polym. Sci., 2010, vol. 35, no. 8, pp. 959–1023.

    Article  Google Scholar 

  10. Grishin, D.F., Kolyakina, E.V., Pavlovskaya, M.V., et al., Am. Chem. Soc. Symp. Ser., 2009, vol. 1024, no. 7, pp. 95–114.

    CAS  Google Scholar 

  11. Wannemacher, T., Macromol. Symp., 2003, vol. 202, pp. 11–23.

    Article  CAS  Google Scholar 

  12. Owen, D., Degradation and Stabilization of Poly (Vinyl Chloride, London: Elsevier Applied Science, 1984.

    Google Scholar 

  13. Kolyakina, E.V., Lazarev, M.A., Pavlovskaya, M.V., et al., Russ. Chem. Bull., 2010, vol. 59, no. 8, pp. 1556–1564.

    Article  CAS  Google Scholar 

  14. Zubenko, D., Tsentalovich, Yu., Lebedeva, N., et al., J. Org. Chem., 2006, vol. 71, no. 16, pp. 6044–6052.

    Article  CAS  Google Scholar 

  15. Weissberger, A., Proskauer, E., Riddick, J., and Toops, E., Organic Solvents. Physical Properties and Methods of Purification, New York: Interscience, 1955.

    Google Scholar 

  16. Entsiklopediya polimerov (Polymer Encyclopedia), Moscow: Sov. Entsiklopediya, 1972, vol. 1.

  17. Gaussian 03, Revision E.01, http://www.gaussian.com.

  18. Hohenberg, P. and Kohn, W., Phys. Rev. B, 1964, vol. 136, p. 864.

    Article  Google Scholar 

  19. Becke, A.D., Phys. Rev. A, 1988, vol. 38, p. 3098.

    Article  CAS  Google Scholar 

  20. Perdew, J.P., Phys. Rev. B, 1986, vol. 33, p. 8822.

    Article  Google Scholar 

  21. Grishin, D.F., Ignatov, S.K., Razuvaev, A.G., et al., Polym. Sci., Ser. A, 2001, vol. 43, no. 10, pp. 989–994.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Lobachevsky Nizhni Novgorod State University, pr. Lenina 27, Nizhni Novgorod, 603950, Russia

    M. V. Pavlovskaya, N. N. Smirnova, A. V. Markin & D. F. Grishin

Authors
  1. M. V. Pavlovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. N. Smirnova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Markin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. F. Grishin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. V. Pavlovskaya.

Additional information

Original Russian Text © M.V. Pavlovskaya, N.N. Smirnova, A.V. Markin, D.F. Grishin, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 3, pp. 360–366.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pavlovskaya, M.V., Smirnova, N.N., Markin, A.V. et al. Synthesis of block copolymers from polyvinyl chloride prepared in the presence of nitroxyl radicals of the imidazoline series. Russ J Appl Chem 87, 324–330 (2014). https://doi.org/10.1134/S1070427214030136

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427214030136

Keywords

Search

Navigation