Skip to main content
SpringerLink
Log in

Intercalation of lithium into porous titanium oxide produced by anodic oxidation

  • Inorganic Synthesis and Industrial Inorganic Chemistry
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Process of lithium intercalation in a 1 M anhydrous propylene carbonate solution of LiClO4 into porous titanium oxide produced by anodic oxidation of titanium in aqueous and nonaqueous electrolytes containing fluoride ions was studied. It is shown that the mass of intercalated lithium, which determines the efficiency of the cathodic reaction of lithium titanate formation, strongly depends on the specific surface area of the oxide. The results obtained make it possible to formulate approaches to solving the problem of raising the reversible electrical capacity of a lithium power source.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Zobenkova, V.A. and Churikov, A.V., Elektrokhim. Energet., 2004, vol. 4, no. 1, pp. 29–35.

    CAS  Google Scholar 

  2. Natarajan, C., Setoguchi, K., and Nogami, G., Electrochim. Acta, 1998, vol. 43, pp. 3371–3374.

    Article  CAS  Google Scholar 

  3. Buldakov, D.A., Petukhov, D.I., Kolesnik, I.V., et al., Ros. Nanotekhnol., 2009, vol. 4, nos. 5–6, pp. 78–82.

    Google Scholar 

  4. Roberts, M., Johns, P., Owen, J., et al., J. Mater. Chem., 2011, vol. 21, pp. 9876–9890.

    Article  CAS  Google Scholar 

  5. Guan, D.S. and Wang, Y., J. Nanoscale, 2012, vol. 4, pp. 2968–2977.

    Article  CAS  Google Scholar 

  6. Grilikhes, S.Ya., Elektrokhimicheskoe polirovanie (Electrochemical Polishing), Leningrad: Mashinostroenie, 1976.

    Google Scholar 

  7. Raja, K.S., Gandhi, T., and Misra, M., Electrochem. Commun., 2007, no. 9, pp. 1069–1076.

    Google Scholar 

  8. Macak, J. and Schmuki, P., Electrochim. Acta, 2006, vol. 52(3), pp. 1258–1264.

    Article  CAS  Google Scholar 

  9. Haring, A., Morris, A., and Hu, M., Materials, 2012, no. 5, pp. 1890–1909.

    Google Scholar 

  10. Lafont, L., Carta, D., Mountjoy, G., et al., J. Phys. Chem., 2010, vol. 114, pp. 1372–1378.

    CAS  Google Scholar 

  11. Kuhn, A., Baehtz, C., and Garcia-Alvarado, F., J. Power Sources, 2007, vol. 174, pp. 421–427.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State Polytechnic University, Polytechnicheskaya ul. 29, St. Petersburg, 195251, Russia

    V. V. Maslov, V. P. Yurkinskii & I. A. Samsonova

Authors
  1. V. V. Maslov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. P. Yurkinskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Samsonova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Maslov.

Additional information

Original Russian Text © V.V. Maslov, V.P. Yurkinskii, I.A. Samsonova, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 2, pp. 203–209.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Maslov, V.V., Yurkinskii, V.P. & Samsonova, I.A. Intercalation of lithium into porous titanium oxide produced by anodic oxidation. Russ J Appl Chem 87, 184–189 (2014). https://doi.org/10.1134/S1070427214020104

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427214020104

Keywords

Search

Navigation