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Oxidation of 2,4-dinitrotoluene with ozone in the presence of a stop reagent

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Liquid-phase oxidation of 2,4-dinitrotoluene with ozone in the presence of acetic anhydride as stop reagent and manganese(II) acetate as catalyst was studied. The major products of oxidation with ozone in acetic anhydride are 2,4-dinitrobenzyl alcohol (65.8%) and 2,4-dinitrobenzaldehyde (18.8%) in the form of the corresponding acetates. A reaction scheme accounting for the results obtained is considered.

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Authors and Affiliations

  1. Institute of Chemical Technologies, Dal’ East-Ukrainian National University, Gorodok Shorsa 17A, Rubezhnoe, Lugansk oblast, 19011, Ukraine

    A. G. Galstyan, V. V. Lysak & G. A. Galstyan

Authors
  1. A. G. Galstyan
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  2. V. V. Lysak
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  3. G. A. Galstyan
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Correspondence to A. G. Galstyan.

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Original Russian Text © A.G. Galstyan, V.V. Lysak, G.A. Galstyan, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 1, pp. 35–39.

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Galstyan, A.G., Lysak, V.V. & Galstyan, G.A. Oxidation of 2,4-dinitrotoluene with ozone in the presence of a stop reagent. Russ J Appl Chem 87, 31–35 (2014). https://doi.org/10.1134/S1070427214010042

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  • DOI: https://doi.org/10.1134/S1070427214010042

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