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Regularities of adsorption of zinc acetate from aqueous solutions onto the surface of modified activated carbons

  • Sorbents and Separation Processes
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Abstract

The dependence of the characteristics of Zn(OAc)2/C catalysts for vinyl acetate synthesis on the solution circulation rate, on the temperature and initial concentration of zinc acetate solution, and on the procedures for modification of activated carbons with oxidants was studied with the aim to achieve uniform distribution of the supported active component (zinc acetate). Oxidation of activated carbons with hydrogen peroxide and nitric acid increases the adsorption rate and the amount of adsorbed zinc acetate. Treatment of the support with acetic acid leads to an increase in the adsorption capacity for zinc acetate, to more uniform distribution of the active component over the surface, and to enhancement of the catalyst activity. The hydrodynamic regime of stirring in the two-phase system consisting of the support and zinc acetate solution is an important factor determining the activity and stability of the zinc acetate catalyst for vinyl acetate synthesis.

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References

  1. Koganovskii, A.M., Levchenko, T.M., and Kirichenko, V.A., Adsorbtsiya rastvorennykh veshchestv (Adsorption of Dissolved Substances), Kiev: Naukova Dumka, 1987.

    Google Scholar 

  2. Gurrath, M., Kuretsky, T., Boehm, H.P., et al., Carbon, 2000, vol. 38, pp. 1241–1255.

    Article  CAS  Google Scholar 

  3. Okhlopkova, L.B., Lisitsyn, A.S., and Likholova, V.A., Appl. Catal., 2000, vol. 204, no. 26, pp. 229–240.

    Article  CAS  Google Scholar 

  4. Hutchings, G.J., S. Afr. J. Chem., 1985, vol. 38, pp. 25–30.

    CAS  Google Scholar 

  5. Hoang Kim Bong, Pushnyak, A.N., and Chobanu, M.M., Zh. Prikl. Khim., 1989, vol. 62, no. 4, pp. 749–754.

    Google Scholar 

  6. Hoang Kim Bong, Temkin, O.N., Fomicheva, T.V., and Shestakov, G.K., Zh. Prikl. Khim., 1997, vol. 70, no. 11, pp. 1782–1786.

    Google Scholar 

  7. Hoang Kim Bong, Temkin, O.N., and Kurlyandskaya, I.I., in Sbornik V Mezhdunarodnoi konferentsii “High Technology” (Proc. V Int. Conf. “High Technology”), Yaroslavl, May 19–21, 1998, pp. 95–97.

    Google Scholar 

  8. Hoang Kim Bong, Temkin, O.N., Ivan Chavez Abanto, and Chobanu, M.M., Zh. Prikl. Khim., 1989, vol. 62, no. 6, pp. 1247–1250.

    Google Scholar 

  9. Panfilov, A.A., Vasil’eva, I.B., and Kamenko, B.L., Khim. Prom-st., 1970, no. 3, pp. 177–179.

    Google Scholar 

  10. Temkin, O.N., Shestakov, G.K., and Treger, Yu.A., Atsetilen: khimiya, mekhanizmy reaktsii, tekhnologiya (Acetylene: Chemistry, Reaction Mechanisms, Technology), Moscow: Khimiya, 1991.

    Google Scholar 

  11. Hoang Kim Bong and Temkin, O.N., Zh. Prikl. Khim., 1998, vol. 71, no. 1, pp. 92–98.

    Google Scholar 

  12. Romenskii, A.V., Loboiko, A.Ya., and Atroshchenko, V.I., Khim. Tekhnol., 1986, vol. 6, pp. 39–42.

    Google Scholar 

  13. Likholobov, V.A. and Lisitsyn, A.I., Zh. Vses. Khim. O-va. im. D.I. Mendeleeva, 1989, vol. 34. no. 3, pp. 340–348.

    Google Scholar 

  14. Plaksin, G.V., Semikolenov, V.A., and Zaikovskii, V.I., React. Kinet. Catal Lett., 1998, vol. 63, no. 1, pp. 157–163.

    Article  CAS  Google Scholar 

  15. Skelton, D.C., Tobin, R.G., and David, K., J. Phys. Chem., 1999, vol. 103, pp. 964–971.

    CAS  Google Scholar 

  16. Temkin, O.N., Abanto-Chavez, H.I., and Hoang Kim Bong, Kinet. Katal., 2000, vol. 41, no. 5, pp. 701–718.

    Google Scholar 

  17. Hoang Huu Binh, Abanto Chavez, H.I., Kozhemyakina, I.A., et al., Zh. Prikl. Khim., 2003, vol. 76, no. 9, pp. 1458–1464.

    Google Scholar 

  18. Hoang Huu Binh, Specific Features of Formation and Technology of Zinc Acetate Catalysts for Vinyl Acetate Synthesis, Cand. Sci. Dissertation, Moscow, 2004.

    Google Scholar 

  19. Kiselev, A.V., Prakticheskie raboty po adsorbtsii i gazovoi khromatografii (Practical Works on Adsorption and Gas Chromatography), Moscow: Mosk. Gos. Univ., 1968.

    Google Scholar 

  20. Hoang Kim Bong and Temkin, O.N., Zh. Prikl. Khim., 1997, vol. 70, no. 12, pp. 1960–1966.

    Google Scholar 

  21. Mitall, K.L. and Lindman, B., Abstracts of Papers, Workshop on the Adsorption and Sorbents, New York: Plenum, 1984, vol. 1, p. 706.

    Google Scholar 

  22. Rubio, J. and Kitchener, J.A., J. Colloid Interface Sci., 1976, vol. 57, no. 1, pp. 132–142.

    Article  CAS  Google Scholar 

  23. Baranova, S.N., Saranchuk, V.I., and Sapunov, V.A., Khimicheskie produkty iz uglya (Chemical Products from Carbon), Baranova, S.I., Ed., Kiev: Naukova Dumka, 1983.

  24. Tarkovskaya, I.A., Okislennyi ugol’ (Oxidized Carbon), Kiev: Naukova Dumka, 1981.

    Google Scholar 

  25. Koganovskii, A.M., Levchenko, T.M., and Kirichenko, V.A., Zh. Prikl. Khim., 1989, vol. 78, no. 2, pp. 231–237.

    Google Scholar 

  26. Kurlyandskaya, I.I., Glazunova, E.D., Temkin, O.N., and Hoang Kim Bong, Abstracts of Papers, Int. Symp. “Carbon for Catalysis” (Carbocat-2004), Lausanne (Switzerland), July 18–20, 2004, p. 225.

    Google Scholar 

  27. Hoang Kim Bong, Temkin, O.N., Hoang Huu Binh, and Yamandiy, D.I., J. Chem. Chem. Eng., 2011, vol. 5, pp. 473–477.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Lomonosov Moscow State University of Fine Chemical Technologies, Moscow, Russia

    Hoang Kim Bong, Hoang Huu Binh, I. I. Kurlyandskaya, A. N. Nyrkova, D. I. Yamandii & O. N. Temkin

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  1. Hoang Kim Bong
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  2. Hoang Huu Binh
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  3. I. I. Kurlyandskaya
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  4. A. N. Nyrkova
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  5. D. I. Yamandii
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  6. O. N. Temkin
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Correspondence to Hoang Kim Bong.

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Original English Text © Hoang Kim Bong, Hoang Huu Binh, I.I. Kurlyandskaya, A.N. Nyrkova, D.I. Yamandii, O.N. Temkin, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 11, pp. 1740–1751.

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Bong, H.K., Binh, H.H., Kurlyandskaya, I.I. et al. Regularities of adsorption of zinc acetate from aqueous solutions onto the surface of modified activated carbons. Russ J Appl Chem 86, 1691–1701 (2013). https://doi.org/10.1134/S1070427213110104

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  • DOI: https://doi.org/10.1134/S1070427213110104

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