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Fluorescence quenching features in non-conjugated diacetylene oligomers

  • Physicochemical Investigation of Systems and Processes
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Abstract

It was found that, in diacetylene oligomers constisred of monomer units with an non-conjugated system of π-electrons, the efficiency of fluorescence quenching depends on the chain length within the range from 2 to 40 repeating units. This effect is consistent with the model of propagation of delocalized excitons in a noncovalent aggregate of several oligomer chains. The result obtained in the study confirms the assumption that a collective effect due to excitons can exist in a supramolecular aggregate of non-conjugated molecules.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    Yu. G. Vlasov, A. A. Kruchinin & D. S. Ryabukhin

Authors
  1. Yu. G. Vlasov
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  2. A. A. Kruchinin
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  3. D. S. Ryabukhin
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Correspondence to A. A. Kruchinin.

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Original English Text © Yu.G. Vlasov, A.A. Kruchinin, D.S. Ryabukhin, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 11, pp. 1711–1717.

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Vlasov, Y.G., Kruchinin, A.A. & Ryabukhin, D.S. Fluorescence quenching features in non-conjugated diacetylene oligomers. Russ J Appl Chem 86, 1663–1669 (2013). https://doi.org/10.1134/S1070427213110062

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  • DOI: https://doi.org/10.1134/S1070427213110062

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