Abstract
Treatment of fresh phosphohemihydrate obtained in processing the Khibiny apatite concentrate by hemihydrate sulfuric acid method was suggested by solutions containing alkali metal fluorides. It was shown that such treatment reduces the transit time of low-hydrated rare earth elements phosphates contained therein, which are poorly soluble in mineral acids, into the acid form from 2 months to 4–8 h.
Similar content being viewed by others
References
Lokshin, E.P., Lebedev, V.N., Masloboev, V.A. et al., Mineral’noe syr’e, 2000, no. 7, pp. 122–126.
Kuzina, T.I., Slivko, T.A., Zimina, G.V., and Komissarova, L.N., Izv. Vuzov. Tsv. Metallurgiya, 1994, nos. 1–2, pp. 68–70.
Lokshin, E.P. and Tareeva, O.A., Russ. J. Appl. Chem., 2008. vol. 81, no. 1, pp. 1–8.
Lokshin, E.P., Vershkova, Yu.A., Ivlev, K.G., and Tareeva, O.A., Zh. Neorg. Khim., 2004, vol. 49, no. 4, pp. 707–710.
Lokshin, E.P., Tareeva, O.A., Zh. Neorg. Khim., 2007, vol. 52, no. 12, pp. 1–5.
Ryss, I.G., Khimiya ftora i ego neorganicheskikh soedinenii (Fluorine Chemistry and Its Inorganic Compounds), Moscow: Goskhimizdat, 1956.
Frayret, J., Castetbon, A., Troube, G., and Potin-Gautier, M., Chem. Phys. Lett., 2006, vol. 427, nos. 4–6, pp. 356–364.
Laitinen, H.A., and Harris, W.E., Chemical Analysis: An Advanced Text and Reference, McGraw-Hill, 1975.
Kreshkov, A.P., Osnovy analiticheskoi khimii (Principles of Analytical Chemistry), vol. 2, Moscow: Khimiya, 1971.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.P. Lokshin, O.A. Tareeva, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 11, pp. 1686–1690.
Rights and permissions
About this article
Cite this article
Lokshin, E.P., Tareeva, O.A. Activation of leaching of rare earth elements from phosphohemihydrate. Russ J Appl Chem 86, 1638–1642 (2013). https://doi.org/10.1134/S1070427213110025
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427213110025