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A polylinear regression model taking into account the cross effects of the structure and temperature in the reactions of phenyloxirane with benzoic acids, catalyzed by pyridines: Evidence of the isoparametricity phenomenon

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Abstract

The joint effect of the structure and temperature on the rate of the reactions of phenyloxirane with Y-substituted benzoic acids in acetonitrile, catalyzed by X-substituted pyridines, was studied. A polylinear regression model that adequately describes the effects of cross-varied factors was calculated. Owing to intensive interaction of the effects of the substituents X and temperature, experimental evidence for the isoparametricity phenomenon was obtained.

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Correspondence to I. V. Shpan’ko.

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Original Russian Text © I.V. Shpan’ko, I.V. Sadovaya, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 8, pp. 1282–1287.

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Shpan’ko, I.V., Sadovaya, I.V. A polylinear regression model taking into account the cross effects of the structure and temperature in the reactions of phenyloxirane with benzoic acids, catalyzed by pyridines: Evidence of the isoparametricity phenomenon. Russ J Appl Chem 86, 1256–1261 (2013). https://doi.org/10.1134/S107042721308017X

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  • DOI: https://doi.org/10.1134/S107042721308017X

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