Abstract
The joint effect of the structure and temperature on the rate of the reactions of phenyloxirane with Y-substituted benzoic acids in acetonitrile, catalyzed by X-substituted pyridines, was studied. A polylinear regression model that adequately describes the effects of cross-varied factors was calculated. Owing to intensive interaction of the effects of the substituents X and temperature, experimental evidence for the isoparametricity phenomenon was obtained.
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References
Pal’m, V.A., Osnovy kolichestvennoi teorii organicheskikh reaktsii (Fundamentals of the Quantitative Theory of Organic Reactions), Leningrad: Khimiya, 1977
Lee, I., Chem. Soc. Rev., 1990, vol. 19, no. 3, pp. 317–333.
Shpan’ko, I.V., Mendeleev Commun., 1991, no. 4, pp. 119–120.
Lee, I., Adv. Phys. Org. Chem., 1991, vol. 27, pp. 57–117.
Shpanko, I.V., Kim, S.I., Koh, H.J., and Lee, I., Bull. Korean Chem. Soc., 1995, vol. 16, no. 6, pp. 533–538.
Shpan’ko, I.V., Teor. Eksp. Khim., 1999, vol. 35, no. 2, pp. 67–78.
Shpan’ko, I.V., Teor. Eksp. Khim., 2001, vol. 37, no. 5, p. 265–279.
Paquin, A.M., Epoxidverbindungen und Epoxidharze, Berlin: Springer, 1958.
Kas’yan, L.I., Kas’yan, A.O., Okovityi, S.I., and Tarabara, I.N., Alitsiklicheskie epoksidnye soedineniya. Reaktsionnaya sposobnost’ (Alicyclic Epoxy Compounds: Reactivity), Dnepropetrovsk: Dnipropetrovsk. Univ., 2003.
Aziridines and Epoxides in Organic Synthesis, Yudin, A.K., Ed., Weinheim: Wiley, 2006.
Dryuk, V.G., Kartsev, V.G., and Voitsekhovskaya, M.A., Oksirany — sintez i biologicheskaya aktivnost’ (Oxiranes: Synthesis and Biological Activity), Moscow: Bogorodskii Pechatnik, 1999.
Kas’yan, O.A., Golodaeva, E.A., Tsigankov, A.V., and Kas’yan, L.I., Zh. Org. Khim., 2002, vol. 38, no. 7, pp. 1661–1670.
Shpan’ko, I.V. and Sadovaya, I.V., Kinet. Katal., 2011, vol. 52, no. 5, pp. 662–669.
Shpan’ko, I.V., Sadovaya, I.V., and Kitaigorodskii, A.M., Ukr. Khim. Zh., 2003, vol. 69, no. 6, pp. 111–115.
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Original Russian Text © I.V. Shpan’ko, I.V. Sadovaya, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 8, pp. 1282–1287.
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Shpan’ko, I.V., Sadovaya, I.V. A polylinear regression model taking into account the cross effects of the structure and temperature in the reactions of phenyloxirane with benzoic acids, catalyzed by pyridines: Evidence of the isoparametricity phenomenon. Russ J Appl Chem 86, 1256–1261 (2013). https://doi.org/10.1134/S107042721308017X
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DOI: https://doi.org/10.1134/S107042721308017X