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Catalytic synthesis of certain perfluorinated ketones and study of their structure by 19F NMR spectroscopy

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An Erratum to this article was published on 01 December 2013

Abstract

An efficient catalyst of a perfluorinated ketone synthesis of a high selectivity in the absence of solvent was proposed. Products of reaction of perfluorinated fluorides of various structures with tetrafluoroethylene and hexafluoropropylene in the presence of efficient catalysts without solvent were examined. The structure of the resulting products and their isomeric composition were identified by 19F NMR spectrscopy.

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References

  1. US Patent 3185734, 1965. Novel Poly-fluoro-substituted Ketones and Their Preparation from Polyfluoro Acid Fluorides.

  2. US Patent 4136121, 1979. Process for the Preparation of Fluorine-Containing Ketones.

  3. RF Patent 2279422, 2006.

  4. Smith, R.D., Fawcett, F.S., and Coffman, D.D., J. Am. Chem. Soc., 1962, vol. 84, p. 4285.

    Article  CAS  Google Scholar 

  5. Kolenko, I.P., Plashkin, V.S., and Ovchinnikov, G.F., Zh. Vses. Khim. Obshch. im. D.I.Mendeleeva, 1974, vol. 19, p. 707.

    CAS  Google Scholar 

  6. USSRInventor’s Certificate 569554, A Method for Producing a Fluorinated Ketone, 1977.

  7. USSR Inventor’s Certificate 717032, 1978. A method for Producing Perfluoroethylisopropyl Ketone.

  8. US Patent 6478979, 2002, Use of Fluorinated Ketones in Fire Extinguishing Compositions.

  9. US Patent 5387728, 1995. Process for the Preparation of Hexafluoropropene Dimers Having a High Proportion of Perfluoro-(4-methyl-2-pentene).

  10. US Patent 5254774, 1993, Preparation of Hexafluoropropene Oligomers.

  11. RF Patent 2460717, 2012. A Method for Producing Perfluoroethylisopropyl Ketone a Plug Flow Reactor.

  12. RF Patent 2472767, 2013. A Method for Producing Perfluoroethylisopropyl Ketone.

  13. Moldavskii, D.D., Fenichev, I.M., Babenko, Yu.I., et al., Onlain. Zh. “Fluoronye Zametki,” 2011, no. 6, 1979. http://notes.fluorine1.ru/public/2011/6_2011/ru-sindex.html

    Google Scholar 

  14. Tarrant, P. and Stamp, E., Zh. Vses. Khim. Obshch. im. D.I. Mendeleeva, 1970, vol. 15, pp. 34–44.

    Google Scholar 

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Correspondence to I. M. Fenichev.

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Original Russian Text © I.M. Fenichev, V.V. Berenblit, T.A. Bispen, N.V. Lebedev, D.D. Moldavskii, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 8, pp. 1269–1277.

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Fenichev, I.M., Berenblit, V.V., Bispen, T.A. et al. Catalytic synthesis of certain perfluorinated ketones and study of their structure by 19F NMR spectroscopy. Russ J Appl Chem 86, 1243–1251 (2013). https://doi.org/10.1134/S1070427213080156

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  • DOI: https://doi.org/10.1134/S1070427213080156

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