Abstract
Layered natural aluminosilicate, Na+-montmorillonite, was modified with mono- and bis(polyfluoroalkyl) phthalates. The polyfluorinated esters as Na+-montmorillonite modifiers exhibit high organophilizing and hydrophobizing activity, as demonstrated by thermal analysis and IR spectroscopy. A change in the interlayer spacing in the clay was determined by X-ray diffraction. The capability of the modifier for intercalation into the layered structure of the clay depends on the degree of telomerization of the perfluoroalkyl residue.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Kudashev, S.V., Effect of Polyfluorinated Modifiers on the Structure and Properties of Heterochain Polymers, Cand. Sci. Dissertation, Volgograd, 2011.
Novakov, I.A., Rakhimova, N.A., Nistratov, A.V., et al., Tren. Iznos, 2011, vol. 32, no. 4, pp. 344–354.
Novakov, I.A., Rakhimova, N.A., Nistratov, A.V., et al., Khim. Prom-St. Segodnya, 2012, no. 3, pp. 31–44.
Novakov, I.A., Rakhimova, N.A., Nistratov, A.V., et al., Khim. Prom-St. Segodnya, 2012, no. 7, pp. 28–38.
Kudashev, S.V. and Rakhimova, N.A., in Tret’ya Vserossiiskaya shkola-seminar studentov, aspirantov i molodykh uchenykh po napravleniyu “Nanoinzheneriya” (Third All-Russia School-Seminar of Students, Postgraduate Students, and Young Scientists on Nanoengineering), October 13–15, 2010, Moscow-Kaluga, 2010, pp. 66–70.
Novakov, I.A., Rakhimova, N.A., Nistratov, A.V., et al., Zh. Prikl. Khim., 2011, vol. 84, no. 6, pp. 995–1003.
Rakhimova, N.A. and Kudashev, S.V., Zh. Obshch. Khim., 2011, vol. 81, no. 7, pp. 1181–1186.
Rakhimova, N.A. and Kudashev, S.V., Zh. Obshch. Khim., 2011, vol. 81, no. 2, pp. 269–273.
Novakov, I.A., Rakhimova, N.A., Nistratov, A.V., et al., Izv. Volgogr. Tekh. Univ., Ser.: Khim. Tekhnol. Elementoorg. Monom. Polim. Mater.: Mezhvuz. Sborn. Nauchn. Tr., 2011, issue 8, no. 2, pp. 114–121.
Novakov, I.A., Rakhimova, N.A., Nistratov, A.V., et al., Izv. Volgogr. Tekh. Univ., Ser.: Khim. Tekhnol. Elementoorg. Monom. Polim. Mater.: Mezhvuz. Sborn. Nauchn. Tr., 2011, issue 8, no. 2, pp. 121–127.
Novakov, I.A., Rakhimova, N.A., Nistratov, A.V., et al., Izv. Volgogr. Tekh. Univ., Ser.: Khim. Tekhnol. Elementoorg. Monom. Polim. Mater.: Mezhvuz. Sborn. Nauchn. Tr., 2011, issue 8, no. 2, pp. 127–133.
Krasnov, A.P., Rakhimova, N.A., Zubavichus, Ya.V., et al., Tren. Smazka Mash. Mekhan., 2011, no. 2, pp. 29–35.
Ponomarenko, V.A., Krukovskii, S.P., and Alybina, A.Yu., Ftorsoderzhashchie geterotsepnye polimery (Fluorinated Heterochain Polymers), Moscow: Nauka, 1973.
Okada, A. and Kamasumi, M., Polym. Prepr., 1987, vol. 28, pp. 447–448.
Kojima, Y., Usuki, A., Kawasumi, M., et al., J. Polym. Sci., Part A, 1993, vol. 31, pp. 983–986.
Kojima, Y., Usuki, A., Kawasumi, M., et al., J. Polym. Sci., Part A, 1993, vol. 31, pp. 1755–1758.
Rakhimova, N.A. and Kudashev, S.V., Izv. Volgogr. Tekh. Univ., Ser.: Khim. Tekhnol. Elementoorg. Monom. Polim. Mater.: Mezhvuz. Sborn. Nauchn. Tr., 2010, issue 7, no. 2, pp. 49–53.
Rakhimova, N.A. and Kudashev, S.V., Zh. Prikl. Khim., 2010, vol. 83, no. 11, pp. 1905–1910.
Rakhimova, N.A. and Kudashev, S.V., Khim. Prom-st. Segodnya, 2011, no. 11, pp. 25–30.
Boldyrev, A.I., Infrakrasnye spektry mineralov (Infrared Spectra of Minerals), Moscow: Nedra, 1976.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.V. Kudashev, V.F. Zheltobryukhov, O.A. Barkovskaya, V.M. Dronova, K.R. Shevchenko, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 7, pp. 1078–1083.
Rights and permissions
About this article
Cite this article
Kudashev, S.V., Zheltobryukhov, V.F., Barkovskaya, O.A. et al. Modification of Na+-montmorillonite with mono- and bis(polyfluoroalkyl) phthalates. Russ J Appl Chem 86, 1010–1015 (2013). https://doi.org/10.1134/S1070427213070124
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427213070124