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Chemical energy relaxation in cryochemical synthesis of cadmium telluride islands

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Abstract

Results are reported of a study of mechanisms by which an ensemble of nanosize dispersed cadmium telluride particles nucleates on a substrate cooled to a low temperature (down to 77 K) in a synthesis in a vacuum from the vapor phase. Condensation curves, distribution functions, electron diffraction patterns, and micrographs are presented. A model is suggested that satisfactorily accounts for the revealed experimental facts by nucleation of 3D islands on the polymolecular adsorbate layer due to the relaxation of its chemical energy.

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Correspondence to A. P. Belyaev.

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Original Russian Text © A.P. Belyaev, V.P. Rubets, V.V. Antipov, N.S. Bordei, V.I. Zarembo, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 5, pp. 721–728.

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Belyaev, A.P., Rubets, V.P., Antipov, V.V. et al. Chemical energy relaxation in cryochemical synthesis of cadmium telluride islands. Russ J Appl Chem 86, 667–674 (2013). https://doi.org/10.1134/S1070427213050108

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  • DOI: https://doi.org/10.1134/S1070427213050108

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