Abstract
Gas-liquid chromatography was used to study the distribution of 2,2-dimethyl-4-hydroxymethyl-1,3-dioxolane between aqueous and organic liquid phases for seven binary solvents water-hydrocarbon (n-heptane, n-octane, n-decane, benzene, toluene, p-xylene). The distribution coefficients at low solute contents were measured in the temperature range 283–313 K. In all the systems, the ratio between the solute concentrations in the organic and aqueous phases is substantially smaller than unity and grows with increasing temperature. The ratios between the limiting activity coefficients of 2,2-dimethyl-4-hydroxymethyl-1,3-dioxolane in the hydrocarbon and aqueous phases were estimated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Korenman, I.M., Ekstraktsiya v analize organicheskikh veshchestv (Extraction in Analyses of Chemical Substances), Moscow: Khimiya, 1977.
Aarna, A.Ya., Melder, L.I., and Ebber, A.V., Zh. Prikl. Khim., 1979, vol. 52, no. 7, p. 1640.
Korenman, I.M., Konstanty raspredeleniya organicheskikh veshchestv mezhdu dvumya zhidkimi fazami (Distribution Constants of Organic Substances between Two Liquid Phases), Gorki, 1975–1979, nos.1–5.
Korenman, Ya.I., Koeffitsienty raspredeleniya organicheskikh soedinenii: Spravochnik (Distribution Constants of Organic Compounds: Reference Book), Voronezh: Voronezh. Gos. Univ., 1992.
Hansch, C. and Leo, A., Substituent Constants for Correlation Analysis in Chemistry and Biology, New York: John Wiley & Sons Inc., 1979.
Dobryakova, I.E. and Dobryakov, Yu.G., Zh. Prikl. Khim., 2004, vol. 77, no. 11, p. 1768.
Varfolomeev, S.D., The Chem. J., 2009, no. 8, p. 36.
Mushrush, G.W., Beal, E.J., Hardy, D.R., et al., Ind. Eng. Chem. Res., 1999, vol. 38, p. 2497.
RF Patent 2365617.
Chueshov, V.I. et al., Promyshlennaya tekhnologiya lekarstv (Industrial Technology of Medicines), Novosibirsk: MTK-kniga, 2002, vols. 1–2, p. 1274.
Yakovleva, M.A., Prikhod’ko, I.V., Pukinskii, I.B., and Smirnova, N.A., Vestn. SPb Gos. Univ., Ser. 4, 2011, no. 2, p. 117.
Yakovleva, M.A., Vorobyov, E.N., Prikhodko, I.V., et al., 25th Eur. Symp. on Appl. Thermodynamics, Saint-Petersburg, Russia, 2011, p. 276.
Dobryakov, Yu.G., Asprion, N., Khasse, G., et al., Teor. Osn. Khim. Tekhnol., 1997, vol. 31, no. 6, p. 605.
Dobryakova, I.E. and Dobryakov, Yu.G., Zh. Prikl. Khim., 2005, vol. 78, no. 2, pp. 214.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © D.A. Novikov, Yu.G. Dobryakov, N.A. Smirnova, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 3, pp. 429–434.
Rights and permissions
About this article
Cite this article
Novikov, D.A., Dobryakov, Y.G. & Smirnova, N.A. Distribution coefficients of 2,2-dimethyl-4-hydroxymethyl-1,3-dioxolane between aqueous and hydrocarbon liquid phases. Russ J Appl Chem 86, 398–403 (2013). https://doi.org/10.1134/S107042721303018X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S107042721303018X