Abstract
A new kind of dynamic thermoplastic elastomers based on chlorosulfonated polyethylene and lowdensity polyethylene, which combine the advantages of composites of polyolefin with nitrile rubber and of polyolefin with ethylene-propylene rubber and are free of their drawbacks, was developed. The composite undergoes self-cross-linking in the course of processing. The specific features of the structure of the composite, associated with the formation of an intermediate interfacial layer, were revealed. The materials exhibit high strength and are resistant to heat, frost, petroleum products, and ozone.
Similar content being viewed by others
References
Vol’fson, S.I., Dinamicheski vulkanizovannye termoelastoplasty: Poluchenie, pererabotka, svoistva (Vulcanized Thermoelastoplastics: Preparation, Processing, Properties), Moscow: Nauka, 2004.
Polymer Blends, Paul, D.R. and Bucknall, C.B., Eds., New York: Wiley, 2000, vol. 2.
Sugonyako, D.V., Karpov, A.G., Zaikin, A.E., and Bikmulin, R.S., Zh. Prikl. Khim., 2010, vol. 83, no. 6, pp. 990–995.
Safronov, S.A., Gaidadin, A.N., Navrotskii, V.A., and Zarudnyi, Ya.V., Kauchuk Rezina, 2011, no. 5, pp. 15–17.
Safronov, S.A., Gaidadin, A.N., Navrotskii, V.A., and Seregin, A.I., Izv. Volgogr., Gos. Tekh. Univ., Ser.: Khim. Tekhnol. Elementoorg. Monom. Polim. Mater., 2012, vol. 5,issue 9, pp. 159–165.
Ronkin, G.M., Khlorsul’firovannyi polietilen: Tematicheskii obzor (Chlorosulfonated Polyethylene: Topical Review), Moscow: TsNIITEneftekhim, 1977.
Dontsov, A.A., Khlorirovannye polimery (Chlorinated Polymers), Moscow: Khimiya, 1979.
Krasovskii, V.N., Primery i zadachi po tekhnologii pererabotki elastomerov (Examples and Problems on Elastomer Processing Technology), Leningrad: Khimiya, 1984.
Krutova, Z.M., Spravochnik rezinshchika (Handbook of Rubber Manufacturer), Moscow: Khimiya, 1968.
Antunes, C.F., Machado, A.V., and Duin, M. van, Eur. Polym. J., 2011, vol. 47, pp. 1447–1459.
Martin, G., Barrès, C., Sonntag, P., et al., Eur. Polym. J., 2009, vol. 45, pp. 3257–3268.
Martin, G., Barrès, C., Cassagnau, P., et al., Polymer, 2008, vol. 49, pp. 1892–1901.
l’Abee, R., Goossens, H., and Duin, M. van, Polymer, 2008, vol. 49, pp. 2288–2297.
Gaidadin, A.N., Ankudinova, N.V., and Navrotskii, V.A., Plast. Massy, 2011, no. 7, pp. 9–12.
Novakov, I.A., Vol’fson, S.I., Novopol’tseva, O.M., and Krakshin, M.A., Reologicheskie i vulkanizatsionnye svoistva elastomernykh kompozitsii (Rheological and Vulcanization Properties of Elastomeric Composites), Moscow: Akademkniga, 2006.
Baranov, A.I., Erina, N.A., Medintseva, T.I., et al., Vysokomol. Soedin., Ser. A, 2001, vol. 43, no. 11, pp. 2001–2008.
Kuleznev, V.N., Smesi polimerov (Polymer Blends), Moscow: Khimiya, 1980.
Nesterov, A.E., Termodinamika rastvorov i smesei polimerov (Thermodynamics of Polymer Solutions and Blends), Kiev: Naukova Dumka, 1984.
Dolinskaya, R.M., Kauchuk Rezina, 2003, no. 6, pp. 14–16.
Sukhanov, P.P., Perukhin, M.Yu., and Arkhireev, V.P., Plast. Massy, 2011, no. 1, pp. 12–14.
Migal’, S.S., Kauchuk Rezina, 1999, no. 1, pp. 9–11.
Litvinov, V.M., Macromolecules, 2006, vol. 39, pp. 8727–8741.
Nersasian, A., King, K.F., Johnson, P.R., J. Appl. Polym. Sci., 1964, vol. 8, pp. 337–354.
Gaidadin, A.N., Petryuk, I.P., and Zarudnii, Ya.V., Izv. Volgogr., Gos. Tekh. Univ., Ser.: Khim. Tekhnol. Elementoorg. Monom. Polim. Mater., 2011, vol. 2,issue 8, pp. 106–109.
Makarov, V.G. and Koptenarmusov, V.B., Promyshlennye termoplasty: Spravochnik (Commercial Thermoplastics: Handbook), Moscow: Khimiya, 2003.
Zaikin, A.E., Shurekova, I.A., and Bukmullin, R.S., Vestn. Kazansk. Tekhnol. Univ., 2008, no. 5, pp. 119–123.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.A. Safronov, A.N. Gaidadin, A.V. Kuratova, V.A. Navrotskii, D.A. Kutsov, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 12, pp. 2056–2067.
Rights and permissions
About this article
Cite this article
Safronov, S.A., Gaidadin, A.N., Kuratova, A.V. et al. Dynamic thermoplastic elastomer based on chlorosulfonated polyethylene. Russ J Appl Chem 85, 1939–1949 (2012). https://doi.org/10.1134/S1070427212120245
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427212120245