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Synthesis and photophysical properties of new carbon-chain copolymers with europium-containing and carbazole fragments in pendant chains

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Functionalized polynorbornenes with terpyridine and carbazole groups in pendant chains were prepared by metathesis copolymerization. The polymeric products prepared react with europium thenoyltrifluoroacetonate to form new carbon-chain copolymers with different ratios of organic and europium-containing units. The polymeric materials prepared were characterized by IR and NMR spectroscopy, gel permeation chromatography, differential scanning calorimetry, and elemental analysis. All the europium-containing copolymers exhibit strong metal-centered photoluminescence in solution and in thin film.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhni Novgorod, Russia

    A. V. Rozhkov, L. N. Bochkarev, G. V. Basova & G. A. Abakumov

Authors
  1. A. V. Rozhkov
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  2. L. N. Bochkarev
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  3. G. V. Basova
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  4. G. A. Abakumov
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Corresponding author

Correspondence to A. V. Rozhkov.

Additional information

Original Russian Text © A.V. Rozhkov, L.N. Bochkarev, G.V. Basova, G.A. Abakumov, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 12, pp. 2046–2055.

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Rozhkov, A.V., Bochkarev, L.N., Basova, G.V. et al. Synthesis and photophysical properties of new carbon-chain copolymers with europium-containing and carbazole fragments in pendant chains. Russ J Appl Chem 85, 1930–1938 (2012). https://doi.org/10.1134/S1070427212120233

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  • DOI: https://doi.org/10.1134/S1070427212120233

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